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Heat capacity and thermodynamic functions of La(VO4)1–x (PO4) x solid solutions at low temperatures

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Abstract

Continuous monazite solid solutions La(VO4)1–х (PO4) х were prepared by ceramic technology. Heat capacities of three samples (х = 0.25, 0.50, and 0.75) were measured by adiabatic calorimetry at low temperatures (5–350 K). Thermodynamic functions were calculated in the range of temperatures studied.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. P. Kritskaya, M. A. Ryumin, G. E. Nikiforova, A. V. Tyurin & K. S. Gavrichev

Authors
  1. A. P. Kritskaya
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  2. M. A. Ryumin
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  3. G. E. Nikiforova
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  4. A. V. Tyurin
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  5. K. S. Gavrichev
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Correspondence to A. P. Kritskaya.

Additional information

Original Russian Text © A.P. Kritskaya, M.A. Ryumin, G.E. Nikiforova, A.V. Tyurin, K.S. Gavrichev, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 1, pp. 74–80.

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Kritskaya, A.P., Ryumin, M.A., Nikiforova, G.E. et al. Heat capacity and thermodynamic functions of La(VO4)1–x (PO4) x solid solutions at low temperatures. Russ. J. Inorg. Chem. 62, 77–83 (2017). https://doi.org/10.1134/S0036023617010090

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  • DOI: https://doi.org/10.1134/S0036023617010090

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