Skip to main content
SpringerLink
Log in

Synthesis and ionic conduction of sodium titanate Na2Ti3O7

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Chemical and phase transformations in the course of synthesis of sodium titanate Na2Ti3O7 have been studied. Prepared sodium titanates have been characterized by X-ray powder diffraction analysis, scaning electron microscopy, and impedance spectroscopy, their electrochemical testing has been conducted. Mechanochemical interaction of titanium dioxide and sodium carbonate at the grinding stage has been revealed. The utilization of mesoporous titanium dioxide have been shown to provide a considerable decrease of final annealing temperature. Thus obtained titanates exhibit high electrochemical capacity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D. Hamani, J. M. Tarascon, and P. Rizier, Electrochem. Commun. 13, 938 (2011).

    Article  CAS  Google Scholar 

  2. N. Yabuuchi, K. Kubota, M. Dahbi, and Sh. Komaba, Chem. Rev. 114, 11636 (2014).

    Article  CAS  Google Scholar 

  3. A.-L. Sauvet, S. Baliteau, C. Lopez, and P. Fabry, J. Solid State Chem. 177, 4508 (2004).

    Article  CAS  Google Scholar 

  4. St. Andersson and A. D. Wadsley, Acta Crystallogr. 14, 1245 (1961).

    Article  CAS  Google Scholar 

  5. Pr. Senguttuvan, Gv. Rousse, V. Seznec, et al., Chem. Mater. 23, 4109 (2011).

    Article  CAS  Google Scholar 

  6. M. Holzinger, J. Maier, and W. Sitte, Solid State Ionics 86–88, 1055 (1996).

    Article  Google Scholar 

  7. Y. V. Kolen’ko, K. A. Kovnir, A. I. Gavrilov, et al., J. Phys. Chem. B 110, 4030 (2006).

    Article  Google Scholar 

  8. J. Ramirez-Saldago, E. Djurado, and P. Fabry, J. Eur. Cer. Soc. 24, 2477 (2004).

    Article  Google Scholar 

  9. V. Meynen, P. Cool, and E. F. Vansant, Micropor. Mesopor. Mat. 125, 170 (2009).

    Article  CAS  Google Scholar 

  10. I. A. Stenina, S. S. Bukalov, T. L. Kulova, et al., Nanotechnol. Russ. 10, 865 (2015).

    Article  CAS  Google Scholar 

  11. P. Thomas and D. Billaud, Electrochim. Acta 47, 3303 (2002).

    Article  CAS  Google Scholar 

  12. A. B. Yaroslavtsev, T. L. Kulova, and A. M. Skundin, Russ. Chem. Rev. 84, 826 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. A. Stenina & A. B. Yaroslavtsev

  2. Moscow State University, Moscow, 119991, Russia

    L. D. Kozina

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    T. L. Kulova, A. M. Skundin & A. A. Chekannikov

Authors
  1. I. A. Stenina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. D. Kozina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. L. Kulova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Skundin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Chekannikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. B. Yaroslavtsev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Stenina.

Additional information

Original Russian Text © I.A. Stenina, L.D. Kozina, T.L. Kulova, A.M. Skundin, A.A. Chekannikov, A.B. Yaroslavtsev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 10, pp. 1292–1297.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Stenina, I.A., Kozina, L.D., Kulova, T.L. et al. Synthesis and ionic conduction of sodium titanate Na2Ti3O7 . Russ. J. Inorg. Chem. 61, 1235–1240 (2016). https://doi.org/10.1134/S003602361610020X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602361610020X

Search

Navigation