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Crystal Structures of α- and β-SrCeCuS3

  • Physical Methods of Investigation
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Abstract

The crystal structure of SrCeCuS3, a complex sulfide synthesized for the first time, has been solved using X-ray powder diffraction data. The crystals are orthorhombic, space group Pnma. SrCeCuS3 has two polymorphs: the high-temperature phase of Ba2MnS3 structural type (a = 8.1393(3) Å, b = 4.0587(2) Å, c = 15.9661(2) Å) and the low-temperature phase isostructural to BaLaCuS3 (a = 11.1626(2) Å, b = 4.0970(2) Å, c = 11.5307(1) Å). The incongruent melting temperature and enthalpy of SrCeCuS3 are, respectively, 1486 ± 3 K and 13.4 ± 1.5 J/g.

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Authors and Affiliations

  1. Tyumen State University, ul. Semakova 10, Tyumen, 625003, Russia

    A. V. Ruseikina

  2. Institute of Chemistry and Chemical Engineering, Siberian Branch, Russian Academy of Sciences, ul. Karla Marksa 42, Krasnoyarsk, 660049, Russia

    L. A. Solov’ev

Authors
  1. A. V. Ruseikina
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  2. L. A. Solov’ev
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Correspondence to A. V. Ruseikina.

Additional information

Original Russian Text © A.V. Ruseikina, L.A. Solov’ev, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 4, pp. 504–509.

The results of this work have been reported at the 3rd International Conference on Competitive Materials and Technology Processes (Miskols-Lillafured, Hungary, October 6‒10, 2014) [19].

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Ruseikina, A.V., Solov’ev, L.A. Crystal Structures of α- and β-SrCeCuS3 . Russ. J. Inorg. Chem. 61, 482–487 (2016). https://doi.org/10.1134/S0036023616040161

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  • DOI: https://doi.org/10.1134/S0036023616040161

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