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Synthesis of sorbent based on hydrated hydroxooxotitane

  • Synthesis and Properties of Inorganic Compounds
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Abstract

It was shown that stable titanium(IV) sol resulted from alkaline neutralization of solutions of titanium salts: oxotitanium sulfate TiOSO4 · H2O and oxotitanium ammonium sulfate (NH4)2TiO(SO4)2 · H2O, can be used in the synthesis of spheroidal granulated ion-exchange material as hydrated hydroxooxotitane. A relationship between the nature of initial solution, number of terminal and bridging OH groups in resulting sol, and the sorption properties of hydroxooxotitane prepared by sol-gel method was revealed. Ion-exchange sorption mechanism was suggested on the basis of different dissociating ability of terminal and bridging OH groups. Surface properties of the prepared materials were studied and their porous system was classified.

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Authors and Affiliations

  1. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science Center, Russian Academy of Sciences, Apatity, Murmansk oblast, 184209, Russia

    M. V. Maslova, L. G. Gerasimova & A. I. Knyazeva

Authors
  1. M. V. Maslova
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  2. L. G. Gerasimova
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  3. A. I. Knyazeva
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Correspondence to M. V. Maslova.

Additional information

Original Russian Text © M.V. Maslova, L.G. Gerasimova, A.I. Knyazeva, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 4, pp. 501–507.

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Maslova, M.V., Gerasimova, L.G. & Knyazeva, A.I. Synthesis of sorbent based on hydrated hydroxooxotitane. Russ. J. Inorg. Chem. 60, 442–448 (2015). https://doi.org/10.1134/S0036023615040154

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  • DOI: https://doi.org/10.1134/S0036023615040154

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