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Ruthenium sorption as heterometallic complexes with phosphoryl-containing impregnated sorbents

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Abstract

It is shown that the main features of ruthenium extractive recovery with neutral organophosphorus compounds (L) as [RuNO(NO2)4ML n ] (M = Zn, Cu, Co, Ni; n = 2–3) heterometallic complexes are retained on the sorption recovery with sorbents impregnated with L. The sorbent based on mixed trialkylphosphine oxide can be used for the chromatographic recovery of ruthenium, the extent of total ruthenium recovery at sorption-desorption stages (90–94%) retains after seven cycles.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    G. A. Kostin, T. M. Korda, T. V. Us & V. G. Torgov

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    G. A. Kostin & T. A. Baeva

Authors
  1. G. A. Kostin
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  2. T. A. Baeva
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  3. T. M. Korda
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  4. T. V. Us
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  5. V. G. Torgov
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Corresponding author

Correspondence to G. A. Kostin.

Additional information

Original Russian Text © G.A. Kostin, T.A. Baeva, T.M. Korda, T.V. Us, V.G. Torgov, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 8, pp. 1122–1128.

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Kostin, G.A., Baeva, T.A., Korda, T.M. et al. Ruthenium sorption as heterometallic complexes with phosphoryl-containing impregnated sorbents. Russ. J. Inorg. Chem. 59, 897–902 (2014). https://doi.org/10.1134/S0036023614080129

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  • DOI: https://doi.org/10.1134/S0036023614080129

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