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Synthesis and physicochemical study of diazabicycloundecene hexamolybdochromate [C9H16N2]H3[CrMo6O18(OH)6] · 2H2O

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Abstract

Quinazoline hexamolybdochromate [C9H16N2]H3[CrMo6O18(OH)6] · 2H2O has been synthesized and studied by mass spectroscopy, X-ray powder diffraction, thermogravimetry, and IR and NMR spectroscopy. The compound crystallizes in triclinic system with the unit cell parameters a = 15.06 Å, b = 13.08 Å, c = 8.17 Å, α = 59.85°, β = 123.15°, γ = 107.01°, V = 1165.62 Å3, ρpycn = 3.58 g/cm3, and Z = 2.

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Authors and Affiliations

  1. Universidad Autónoma Metropolitana-Azcapotzalco, avenida de San Pablo 180, ciudad de México, 02200, México

    S. Holguín Quiñones

  2. Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1/1, Moscow, 119991, Russia

    G. Z. Kaziev, Yu. S. Vlasov, A. V. Oreshkina & O. A. Kirichenko

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. M. Koroteev

Authors
  1. S. Holguín Quiñones
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  2. G. Z. Kaziev
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  3. Yu. S. Vlasov
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  4. A. V. Oreshkina
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  5. O. A. Kirichenko
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  6. A. M. Koroteev
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Corresponding author

Correspondence to S. Holguín Quiñones.

Additional information

Original Russian Text © S. Holguín Quiñones, G.Z. Kaziev, Yu.S. Vlasov, A.V. Oreshkina, O.A. Kirichenko, A.M. Koroteev, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 5, pp. 637–639.

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Holguín Quiñones, S., Kaziev, G.Z., Vlasov, Y.S. et al. Synthesis and physicochemical study of diazabicycloundecene hexamolybdochromate [C9H16N2]H3[CrMo6O18(OH)6] · 2H2O. Russ. J. Inorg. Chem. 59, 469–471 (2014). https://doi.org/10.1134/S003602361405012X

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  • DOI: https://doi.org/10.1134/S003602361405012X

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