Abstract
The crystalline and magnetic structure of the nonstoichiometric intermetallic compound Tm2Fe18 has been investigated in the temperature interval from 3 to 300 K using the methods of neutron diffraction, synchrotron radiation, and ultra-small-angle neutron scattering. A theoretical interpretation of the spin-reorientation transition has been given and the value and temperature dependence of the first constants of magnetic anisotropy for the sublattices of iron and thulium have been determined. Based on the results of experiments and theoretical interpretation of small-angle neutron scattering, a conclusion has been made on a reconstruction of the domain structure upon spin-reorientation phase transition.
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REFERENCES
A. G. Kuchin, W. Iwasieczko, and S. P. Platonov, “The magnetocaloric effect in R2Fe17 intermetallics with different types of magnetic phase transition,” Low Temp. Phys. 41, 985–989 (2015).
A. G. Kuchin, S. P. Platonov, A. V. Korolyov, A. S. Volegov, V. I. Voronin, I. F. Berger, L. V. Elokhina, G. M. Makarova, and E. V. Belozerov, “Magnetism and structure of near-stoichiometric Tm2Fe17 + δ compounds, ” J. Alloys Compd. 599, 26–31 (2014).
Rodriges-Carvajal, “Recent advances in magnetic structure determination by neutron diffraction: The programs for Rietveld refinement,” Phys. B 192, 55–69 (1993).
D. Givord, R. Lemaire, J. M. Moreau, and E. Roudaut, “X-ray and neutron determination of a so-called Th2Ni17-type structure in the lutetium–iron system, ” J. Less-Common Met. 29, 361–369 (1972).
J. B. A. A. Elemans and K. H. J. Buschow, “The magnetic structure of Tm2Fe17,” Phys. Status Solidi A 24, K125–K127 (1974).
D. Givord and R. Lemaire, “Magnetic transition and anomalous thermal expansion in R2Fe17 compounds,” IEEE Trans. Magn. Mag-10 (2), 109–113 (1974).
M. T. Averbuch-Pouchot, R. Chenalier, J. Deportes, B. Kebe, and R. Lemaire, “Anisotropy of the magnetization and of the iron hyperfine field in R2Fe17 compounds,” J. Magn. Magn. Mater. 68, 190–198 (1987).
V. I. Voronin, I. F. Berger, and A. G. Kuchin, “Refining crystal structure of the intermetallic compound Y2Fe17 by powder neutron diffraction,” Phys. Met. Metallogr. 89, 508–513 (2000).
A. V. Andreev, D. Rafaja, J. Kamarad, Z. Arnold, Y. Homma, and Y. Shiokawa, “Magnetic properties of Lu2Fe17 crystals, ” J. Alloys Compd. 361, 48–53 (2003).
J. Park, Y. Jo, J.-G. Park, K. Prokes, S. Welzel, C. H. Lee, N. Kudrevatykh, E. Valiev, A. Pirogov, and D. Sheptyakov, “Magnetization anisotropy of the Tm- and Fe-subsystems in Tm2Fe17,” J. Magn. Magn. Mater. 237, 158–168 (2001).
É. Z. Valiev and V. I. Voronin, “Crystal structure, magnetizations of sublattices, and the spin-reorientation transition in the Er2Fe17N2.18 compound,” Phys. Solid State 52, 927–930 (2010).
J. F. Herbst and J. J. Croat, “Magnetization of R6Fe23 intermetallic compounds: Molecular field theory analysis,” J. Appl. Phys. 55, 3023–3027 (1984).
K. H. J. Buschow, “New developments in hard magnetic materials,” Rep. Prog. Phys. 54, 1123–1214 (1991).
Yu. P. Irkhin and E. V. Rozenfel’d, “Phenomenological theory of magnetic anisotropy of RCo5 compounds,“ Fiz. Tverd. Tela 16, 485–489 (1974).
A. S. Ermolenko, E. V. Rozenfel’d, Yu. P. Irkhin, V. V. Kelarev, A. F. Rozda, S. K. Sidorov, A. N. Pirogov, A. P. Vokhmyanin, “Effect of magnetic anisotropy on the temperature dependence of the magnetization of some compounds of the type RCo5,“ Zh. Eksp. Teor. Fiz. 69, 1743–1752 (1975).
K. P. Belov, A. K. Zvezdin, A. M. Kadomtseva, and R. Z. Levitin, Orientation Transitions in Rare Earth Magnets (Nauka, Moscow, 1979).
E. R. Callen and H. B. Callen, “Anisotropic magnetization, “ J. Phys. Chem. Solids 16, 310–328 (1960).
R. J. Weiss, “Small angle scattering of neutrons, “ Phys. Rev. B 83, 379–389 (1951).
S. Sh. Shil’shtein, V. A. Somenkov, and M. Kalanov, “Neutron refraction at individual domain boundaries in ferromagnets, “ Zh. Eksp. Teor. Fiz. 63, 2214–2220 (1972).
V. Shushunov, V. Glazkov, V. Voronin, E. Valiev, A. Kuchin, L. Maksimov, S. Platonov, and V. Somenkov, International Conference on Neutron Scattering, July 9–13, 2017, DCC, Daejeon Korea (2017).
FUNDING
The work was supported by the Russian Scientific Foundation, grant no. 16-12-10065 in the framework of the state task according to the theme “Potok,” no. AAAA-A18-118020190112-8.
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Valiev, E.Z., Voronin, V.I., Glazkov, V.P. et al. Neutron Diffraction Studies of the Transformation of Magnetic and Domain Structures upon Spin-Reorientation Transition in the Tm2Fe18 Ferrimagnet. Phys. Metals Metallogr. 120, 313–319 (2019). https://doi.org/10.1134/S0031918X1904015X
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DOI: https://doi.org/10.1134/S0031918X1904015X