Skip to main content
SpringerLink
Log in

Crystal Structure and Luminescence of the [DyCl2(H2O)6]Cl Complex

  • SPECTROSCOPY OF CONDENSED MATTER
  • Published:
Optics and Spectroscopy Aims and scope Submit manuscript

Abstract

The crystal structure of the [DyCl2(H2O)6]Cl complex is studied by X-ray diffraction analysis. The crystals are constructed of complex cations [DyCl2(H2O)6]+ and outer-sphere Cl−1 ions. The structure is represented by separate [DyCl2(H2O)6] complexes bound by a dense network of  \({\text{O}{-}\text{H}}\cdots{\text{Cl}}\) hydrogen bonds. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a weakly distorted square antiprism. The results of investigation of the luminescent properties of the complex are presented.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Triboluminescence. Theory, Synthesis, and Application, Ed. by D. O. Olawale, O. O. I. Okoli, R. S. Fontenot, and W. A. Hollerman (Springer, Switzerland, 2016), p. 39. www.springer.com/la/book/9783319388410.

    Google Scholar 

  2. Z. M. Hao, G. C. Yang, X. Z. Song, M. Zhu, X. Meng, S. N. Zhao, S. Y. Song, and H. J. Zhang, J. Mater. Chem. A 2, 237 (2014). https://doi.org/10.1039/C3TA13179C

    Article  Google Scholar 

  3. A. G. Mirochnik, N. V. Petrochenkova, A. S. Shishov, B. V. Bukvetskii, T. B. Emelina, A. A. Sergeev, and S. S. Voznesenskii, Spectrochim. Acta A 155, 111 (2016). https://doi.org/10.1016/j.saa.2015.11.004

    Article  ADS  Google Scholar 

  4. J-C. G. Bunzli, Chem. Rev. 110, 2729 (2010). https://doi.org/10.1021/cr900362e

    Article  Google Scholar 

  5. J-C. G. Bunzli and S. V. Eliseeva, Chem. Sci. 4, 1939 (2013). https://doi.org/10.1039/C3SC22126A

    Article  Google Scholar 

  6. U. Hommerich, E. Nyein, J. A. Freeman, P. Amedzake, S. B. Trivedi, and J. M. J. Zavada, J. Cryst. Growth 287, 230 (2006). https://doi.org/10.1016/j.jcrysgro.2005.11.019

    Article  ADS  Google Scholar 

  7. J. Feng, L. Zhou, S. Y. Song, Z. F. Li, W. Q. Fan, L. N. Sun, Y. N. Yu, and H. J. Zhang, Dalton Trans., 6593 (2009). https://doi.org/10.1039/b906419b

  8. K. Wie, D. P. Machewirth, J. Wenzal, E. Snitzer, and G. H. Sigel, Opt. Lett. 19, 904 (1994). https://doi.org/10.1364/OL.19.000904

    Article  ADS  Google Scholar 

  9. X. D. Huang, Y. Xu, K. Fan, S. S. Bao, M. Kurmoo, and L. M. Zheng, Angew. Chem. 57, 8577 (2018). https://doi.org/10.1002/anie.201804102

    Article  Google Scholar 

  10. M. Venkataravanappa, R. B. Basavaraj, G. P. Darshan, B. D. E. Prasad, S. C. Sharma, P. H. Prabha, and H. Nagabhushana, J. Rare Earths 36, 690 (2018). https://doi.org/10.1016/j.jre.2017.11.013

    Article  Google Scholar 

  11. W. A. Dar, Z. Ahmed, and K. Iftikhar, J. Photochem. Photobiol., A 356, 502 (2018). https://doi.org/10.1016/j.jphotochem.2017.12.017

    Article  Google Scholar 

  12. J. H. Wang, S. Chorazy, K. Nakabayashi, B. Sieklucka, and S. Ohkoshi, J. Mater. Chem. C 6, 473 (2018). https://doi.org/10.1039/C7TC03963H

    Article  Google Scholar 

  13. Q. Su, Z. Pei, L. Chi, H. Zhang, Z. Zhang, and F. J. Zou, J. Alloys Compd. 192, 25 (1993). https://doi.org/10.1016/0925-8388(93)90174-L

    Article  Google Scholar 

  14. X. Liu, Y. Liu, D. Yan, H. Zhu, C. Liu, C. Xu, Y. Liu, and X. Wang, J. Mater. Chem. 22, 16839 (2012). https://doi.org/10.1039/C2JM32741D

    Article  Google Scholar 

  15. B. V. Bukvetskii, A. G. Mirochnik, and P. A. Zhikhareva, Opt. Spectrosc. 126, 195 (2019). https://doi.org/10.1134/S0030400X19030044

    Article  ADS  Google Scholar 

  16. Bruker, SMART and SAINT-Plus. Versions 5.0, Data Collection and Processing Software for the SMART System (Bruker AXS Inc., Madison, WI, USA, 1998).

  17. G. M. Sheldrick, SHELXTL/PC. Versions 5. 10. An Integrated System for Solving, Refining and Displaying Crystal Structures From Diffraction Data (Bruker AXS Inc., Madison, WI, USA, 1998).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, 690022, Vladivostok, Russia

    B. V. Bukvetskii, A. G. Mirochnik & P. A. Zhikhareva

Authors
  1. B. V. Bukvetskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. G. Mirochnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. A. Zhikhareva
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. G. Mirochnik.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Translated by M. Basieva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bukvetskii, B.V., Mirochnik, A.G. & Zhikhareva, P.A. Crystal Structure and Luminescence of the [DyCl2(H2O)6]Cl Complex. Opt. Spectrosc. 128, 323–326 (2020). https://doi.org/10.1134/S0030400X20030054

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0030400X20030054

Keywords:

Search

Navigation