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Synthesis, crystal structure, and luminescence properties of CaY2Ge3O10:Ln3+, Ln = Eu, Tb

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Abstract

The crystal structure and luminescence properties of CaY2Ge3O10:Ln3+ (Ln = Eu, Tb) germanates synthesized via a conventional solid-state reaction and an ethylenediaminetetraacetic acid complexing process are studied. The CaY2 − x Ln x Ge3O10 (Ln = Eu, Tb; x = 0–1.0, 2.0; Δx = 0.1) solid solutions have a monoclinic structure (space group P21/c, Z = 4), in which dopant ions occupy three nonequivalent noncentrosymmetric sites with different Ca2+/Ln3+ ratios. The effect of the synthesis methods, dopant concentrations, and excitation wavelengths on the luminescence properties of the compounds obtained is determined.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    O. A. Lipina, L. L. Surat, M. A. Melkozerova, A. P. Tyutyunnik, I. I. Leonidov & V. G. Zubkov

Authors
  1. O. A. Lipina
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  2. L. L. Surat
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  3. M. A. Melkozerova
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  4. A. P. Tyutyunnik
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  5. I. I. Leonidov
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  6. V. G. Zubkov
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Corresponding author

Correspondence to A. P. Tyutyunnik.

Additional information

Original Russian Text © O.A. Lipina, L.L. Surat, M.A. Melkozerova, A.P. Tyutyunnik, I.I. Leonidov, V.G. Zubkov, 2014, published in Optika i Spektroskopiya, 2014, Vol. 116, No. 5, pp. 751–756.

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Lipina, O.A., Surat, L.L., Melkozerova, M.A. et al. Synthesis, crystal structure, and luminescence properties of CaY2Ge3O10:Ln3+, Ln = Eu, Tb. Opt. Spectrosc. 116, 695–699 (2014). https://doi.org/10.1134/S0030400X14050130

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  • DOI: https://doi.org/10.1134/S0030400X14050130

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