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SAMAROCENECHALCOGENIDES \(\mathbf{[\{Cp}_{\mathbf{2}}^{\mathbf{*}}\mathbf{Sm(THF)}{{\mathbf{\}}}_{\mathbf{2}}}\mathbf{(\mu }\text{-}Q\mathbf{)]}\) (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2

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Abstract

Reactions of decamethylsamarocene monochalcogenides \([{{\{\text{Cp}_{2}^{\mathbf{*}}\text{Sm}(\text{THF})\}}_{\text{2}}}(\mu \text{-}Q)]\) (Cp* = η5-C5(CH3)5; Q = S (1), Se (2), Te (3)) with carbon disulfide are studied. It is established that these reactions lead to the formation of complexes \([{{(\text{Cp}_{2}^{\mathbf{*}}\text{Sm})}_{\text{2}}}(\mu \text{-C}{{\text{S}}_{\text{2}}}Q)]\) (Q = S (4), Se (5), Te (6)), i.e. they can be interpreted as an interaction of Q2– with CS2 in the samarium coordination sphere. The structure of compounds 4-6 was determined by XRD (CCDC CIF files No. 2170732 (4), 2170734 (5), 2170733 (6)). The \(\text{CS}_3^{2-}\) bridging ligand in 4 is coordinated to Sm(III) ions by the μ–κ2(S,S′):κ2(S″,S′) type. The heterochalcogenide complexes 5 and 6 are a mixture of isomers with μ–κ2(S,Q):κ2(S′,Q) (main isomer) and μ–κ2(Q,S):κ2(S′,S) types of CS2Q2– coordination (Q = Se, Te).

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Funding

This work was funded by the Russian Science Foundation (project No. 16-13-10294) and the Ministry of Science and Higher Education of the Russian Federation (projects No. 121031700321-3, 121031700313-8).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    B. Yu. Savkov, T. S. Sukhikh & S. N. Konchenko

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 11, 100561.https://doi.org/10.26902/JSC_id100561

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Savkov, B.Y., Sukhikh, T.S. & Konchenko, S.N. SAMAROCENECHALCOGENIDES \(\mathbf{[\{Cp}_{\mathbf{2}}^{\mathbf{*}}\mathbf{Sm(THF)}{{\mathbf{\}}}_{\mathbf{2}}}\mathbf{(\mu }\text{-}Q\mathbf{)]}\) (Q = S, SE, TE) AS SYNTHETIC EQUIVALENTS OF THE Q2– SYNTHON IN REACTIONS WITH CS2. J Struct Chem 63, 1734–1744 (2022). https://doi.org/10.1134/S0022476622110026

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