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ON THE STABILITY OF THE [Li2Zn2(bpy)(ndc)3] STRUCTURE WITH A METAL-ORGANIC FRAMEWORK

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Abstract

The crystallographic analysis of the structure of a new compound with the metal-organic framework (MOF) [Li2Zn2(bpy)(ndc)3] (bpy = 4,4′-bipyridine, ndc2– = naphthalene-1,4-dicarboxylate) shows that its stability is provided by a body-centered quasi-cubic lattice of nodes, one sixth of which is occupied by ZnO3N tetrahedra. The local concentration of vacant nodes forms bulk channels and cavities in the structure.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Borisov, N. V. Pervukhina & S. A. Magarill

Authors
  1. S. V. Borisov
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  2. N. V. Pervukhina
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  3. S. A. Magarill
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Correspondence to S. V. Borisov.

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The authors declare that they have no conflicts of interests.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 10, 100170.https://doi.org/10.26902/JSC_id100170

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Borisov, S.V., Pervukhina, N.V. & Magarill, S.A. ON THE STABILITY OF THE [Li2Zn2(bpy)(ndc)3] STRUCTURE WITH A METAL-ORGANIC FRAMEWORK. J Struct Chem 63, 1708–1714 (2022). https://doi.org/10.1134/S002247662210016X

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