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CuI COMPLEXES BASED ON DI(2-PYRIDYL) (2-AROYLETHENYL)PHOSPHINE OXIDES: SYNTHESIS, STRUCTURE, AND DARK RED PHOTOLUMINESCENCE

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Abstract

By the interaction of CuI with bis(2-pyridyl)phosphine oxides (2-Py)2RP(O) containing E-1-phenyl-2-aroylethenyl–C(Ph)=CHC(O)R′ (R′ = Ph, 2-thienyl) substituents, [Cu2I2L2] complexes are synthesized. Their structures are based on the rhomboidal Cu2I2 moiety whose copper atoms are N,N′-chelated by the indicated ligands. At room temperature, the crystalline samples of these complexes exhibit dark red photoluminescence (λmax = 680-685 nm) with a charge transfer from the Cu2I2 moiety to the ligand.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (projects Nos. 121031700321-3, 121021000199-6) using the material and facilities of the Baikal Analytical Multi-Access Center, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    S. N. Arbuzova, S. I. Verkhoturova & T. N. Borodina

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Artem΄ev

Authors
  1. S. N. Arbuzova
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  2. S. I. Verkhoturova
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  3. T. N. Borodina
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  4. A. V. Artem΄ev
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Correspondence to A. V. Artem΄ev.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 9, 99099.https://doi.org/10.26902/JSC_id99099

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Arbuzova, S.N., Verkhoturova, S.I., Borodina, T.N. et al. CuI COMPLEXES BASED ON DI(2-PYRIDYL) (2-AROYLETHENYL)PHOSPHINE OXIDES: SYNTHESIS, STRUCTURE, AND DARK RED PHOTOLUMINESCENCE. J Struct Chem 63, 1383–1389 (2022). https://doi.org/10.1134/S0022476622090013

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