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CRYSTALLOGRAPHIC ANALYSIS AND CRYSTAL DYNAMICS OF BORATES WITH A COMPLEX CATION COMPOSITION

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Abstract

As a result of the crystallographic analysis of the structures of borates BaNaSc(BO3)2 (I) and K7CaY2(B5O10)3 (II), a model of the formation of stable atomic groups (templates) with high point symmetry is proposed and a coherent assembly of these groups by the planes of pseudo cubic cation sublattices with the point symmetry spread on the whole structure is shown.

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Funding

The work was supported by the by the Ministry of Science and Higher Education of the Russian Federation, project No. 121031700313-8.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Borisov, S. A. Magarill & N. V. Pervukhina

Authors
  1. S. V. Borisov
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  2. S. A. Magarill
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  3. N. V. Pervukhina
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Correspondence to S. V. Borisov.

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The authors declare that they have no conflict of interests.

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 2, pp. 189-197.https://doi.org/10.26902/JSC_id87125

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Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. CRYSTALLOGRAPHIC ANALYSIS AND CRYSTAL DYNAMICS OF BORATES WITH A COMPLEX CATION COMPOSITION. J Struct Chem 63, 252–259 (2022). https://doi.org/10.1134/S0022476622020068

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  • DOI: https://doi.org/10.1134/S0022476622020068

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