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SYNTHESIS, CRYSTAL STRUCTURES, AND LUMINESCENT PROPERTIES OF Zn(II)/Cd(II) COMPLEXES ASSEMBLED BY 4-AMINOPHENYLHYDROXAMIC ACID

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Abstract

Two coordination complexes, namely [Zn2(4-APha)2(CH3COO)2(H2O)2] (1) and [Cd(4-APha)(CH3COO) (H2O)0.5]4·6H2O (2) (4-APha = 4-aminophenylhydroxamic acid), are synthesized by the solvothermal method. They are characterized by single crystal X-ray diffraction, IR, TGA, and elemental analysis. Structural analyses reveal that both complexes 1 and 2 belong to the monoclinic system, space group C2/c. The difference is that complex 1 shows a binuclear structure and complex 2 displays a 3D structure. It is noteworthy that complex 1 exhibits an excellent thermal stability and no weight loss below 117 °C. Meanwhile, the luminescent properties of complexes 1 and 2 in the solid state are also investigated at room temperature.

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Funding

We gratefully acknowledge financial support of the National Natural Science Foundation of China (No. 21501061), the Natural Science Foundation of Hubei Province (No. 2016CFB147) and Doctoral Foundation Project of Huanggang Normal University (No. 2015001803), Project of Chemical Experiment Teaching Demonstration Center of Huanggang Normal University (No. zj201723, zj201722, zx201724, zx2018004).

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Authors and Affiliations

  1. College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang, People’s Republic of China

    J. Q. Hou & W. W. Dong

  2. Hubei Key Laboratory for Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang, People’s Republic of China

    J. Q. Hou & Y. M. Chen

Authors
  1. J. Q. Hou
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  2. Y. M. Chen
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  3. W. W. Dong
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Correspondence to Y. M. Chen or W. W. Dong.

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Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 10, pp. 1692-1701.https://doi.org/10.26902/JSC_id80912

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Hou, J.Q., Chen, Y.M. & Dong, W.W. SYNTHESIS, CRYSTAL STRUCTURES, AND LUMINESCENT PROPERTIES OF Zn(II)/Cd(II) COMPLEXES ASSEMBLED BY 4-AMINOPHENYLHYDROXAMIC ACID. J Struct Chem 62, 1588–1598 (2021). https://doi.org/10.1134/S0022476621100140

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