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CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

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Abstract

Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

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Funding

The study was supported by the Russian Science Foundation (project No.19-73-00169).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Cherezova, M. O. Barsukova, D. G. Samsonenko & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    S. V. Cherezova

Authors
  1. S. V. Cherezova
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  2. M. O. Barsukova
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  3. D. G. Samsonenko
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  4. V. P. Fedin
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Correspondence to V. P. Fedin.

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Russian Text © The Author(s), 2021, published in Zhurnal Strukturnoi Khimii, 2021, Vol. 62, No. 6, pp. 966-973.https://doi.org/10.26902/JSC_id74427

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Cherezova, S.V., Barsukova, M.O., Samsonenko, D.G. et al. CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS. J Struct Chem 62, 897–904 (2021). https://doi.org/10.1134/S0022476621060093

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  • DOI: https://doi.org/10.1134/S0022476621060093

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