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GENESIS AND STRUCTURAL PROPERTIES OF (Ce1–xMx0.8Ni0.2Oy (M = La, Mg) OXIDES

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Abstract

The genesis and structural properties of (Ce1–xMx)0.8Ni0.2Oy (M = La, Mg; x = 0, 0.2, 0.5, 0.8, 1; 1.0 ≤ y ≤ 1.8) oxides that are promising catalyst precursors are studied. A complex of physicochemical methods (low-temperature nitrogen adsorption, ex situ and in situ powder X-ray diffraction, electron microscopy, Raman spectroscopy, and EDX analysis) is used to show that after the calcination at 500 °C in the oxidizing medium, (Ce1–xMx)0.8Ni0.2Oy become mesoporous materials representing substitutional solid solutions with a cubic fluorite-type structure with supported particles of the Ni-containing phase. When M = La, Ni cations are mainly stabilized in the composition of the Ce–La–Ni–O solid solution, and when M = Mg, they are stabilized in the Mg–Ni–O composition. It is found that La- or Mg-containing samples, as compared to Ce0.8Ni0.2Oy, have highly defective structures and smaller sizes of crystallites (≤ 4 nm, x ≥ 0.5). After thermal treatment of the samples in H2/Не at 800 °C, highly dispersed Ni° particles with a size of 5-10 nm are formed. Metal particles have defects and a polycrystal structure, and they are readily reoxidized in air with the formation of “core@shell” Ni@NiO structures.

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Funding

The work was supported by RFBR (project No. 18-53-45012 IND_a).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E V Matus, I Z Ismagilov, V A Ushakov, O A Stonkus, E Yu Gerasimov, M A Kerzhentsev & Z R Ismagilov

  2. Institute of Coal Chemistry and Chemical Materials Science, Siberian Branch, Russian Academy of Sciences, Kemerovo, Russia

    A P Nikitin & Z R Ismagilov

  3. Novosibirsk State University, Novosibirsk, Russia

    O A Stonkus

  4. Tezpur University, Napaam, Tezpur, Assam, India

    P Bharali

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  1. E V Matus
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  2. I Z Ismagilov
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Matus, E.V., Ismagilov, I.Z., Ushakov, V.A. et al. GENESIS AND STRUCTURAL PROPERTIES OF (Ce1–xMx0.8Ni0.2Oy (M = La, Mg) OXIDES. J Struct Chem 61, 1080–1089 (2020). https://doi.org/10.1134/S0022476620070100

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  • DOI: https://doi.org/10.1134/S0022476620070100

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