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Structural Characterization and Anti-Colon Cancer Activity of a Three-Dimensional Anionic Indium(III) Coordination Polymer

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Abstract

Solvothermal treatment of indium(III) nitrate with flexible pseudo-C3-symmetric tricarboxylic acid in the presence of NaCl at 120 °C for three days in a mixed solvent of DMF and CH3CN yields a new 3D anionic indium carboxylate framework {[(CH3)2NH2)In(L)(Cl)](DMF)}n(1) (H3L = 2,4,6-tris[(4-carboxyphenoxy)methyl]-1,3,5-trimethylbenzene), existing as a three-dimensional framework with a 2-fold interpenetrated network. The as-prepared polymer is characterized by the elemental analysis and single crystal X-ray diffraction. DMF undergoes cleavage to dimethyl ammonium ions incorporated in the pores of the framework. Furthermore, a sonochemical method is used to produce nanostructures of complex 1. Then, the in vitro anti-colon cancer activity of nano-1 is assessed with CCK-8. Annexin V-FITC/ PI and DCFH-DA detection is recruited for the cell apoptosis and the intracellular ROS accumulation assay, respectively.

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Authors and Affiliations

  1. Department of Anorectal, Hospital of Bayannaoer, Bayan Nur, Inner Mongolia, P. R. China

    R. Li & J. Zhang

  2. Department of Neurology, Daqing Oilfield General Hospital, Daqing, Heilongjiang, P. R. China

    D. Deng

Authors
  1. R. Li
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  2. J. Zhang
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  3. D. Deng
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Correspondence to J. Zhang.

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The authors declare that they have no conflict of interests.

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Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 6, pp. 1032–1039.

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Li, R., Zhang, J. & Deng, D. Structural Characterization and Anti-Colon Cancer Activity of a Three-Dimensional Anionic Indium(III) Coordination Polymer. J Struct Chem 61, 979–986 (2020). https://doi.org/10.1134/S0022476620060190

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  • DOI: https://doi.org/10.1134/S0022476620060190

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