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Study of the Crystal Structures of Tetraphenylbismuth Hydrosulfate, Tetraphenylbismuth 2,4-Dinitrobenzenesulfonate, and an Adduct of Tetraphenylbismuth Nitrate with Water

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Abstract

Tetraphenylbismuth hydrosulfate Ph4Bi(OSO2OH) (1), tetraphenylbismuth 2,4-dinitrobenzenesulfonate Ph4Bi(OSO2C6H3(NO2)2-2,4) (2), and tetraphenylbismuth nitrate hydrate Ph4BiNO3·1/3H2O (3) are synthesized by the interaction of pentaphenylbismuth with equimolar amounts of sulfuric, 2,4-dinitrobenzenesulfonic, or nitric acids. The crystal structures of 1–3 are determined by the single crystal X-ray diffraction analysis. In 1 and 2, bismuth atoms are pentacoordinated (C4BiO environment). The 3 crystal contains three types of tetraphenylbismuthonium cations, two of which being coordinated to a nitrate anion and a water molecule.

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Authors and Affiliations

  1. South Ural State University, Chelyabinsk, Russia

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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Correspondence to V. V. Sharutin.

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Russian Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 5, pp. 776–783.

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Sharutin, V.V., Sharutina, O.K. & Senchurin, V.S. Study of the Crystal Structures of Tetraphenylbismuth Hydrosulfate, Tetraphenylbismuth 2,4-Dinitrobenzenesulfonate, and an Adduct of Tetraphenylbismuth Nitrate with Water. J Struct Chem 61, 734–741 (2020). https://doi.org/10.1134/S0022476620050091

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