Skip to main content
SpringerLink
Log in

Frequency Dispersion of the Specific Conductance Coefficient in Aqueous Electrolyte Solutions

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Analytical expressions for the dynamic specific conductance coefficient σ(ω) and the dynamic electroelasticity modulus ∊(ω) are obtained by solving kinetic equations using specific expressions for the potential energy Φab(r) of the interaction between structural units of the solution and the equilibrium radial distribution function gab(r). Friction coefficients βa and βb are calculated numerically; relaxation times τa, τb, τab along with ∊(ω) and σ(ω) values are determined for aqueous solutions of LiCl, NaCl, KCl, and CsCl as functions of the concentration c, density ρ, and temperature T in a wide frequency range ω. The obtained theoretical data are presented in the form of tables and graphs and are compared with experimental results show a satisfactory agreement between them.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. A. Robinson and R. H. Stokes. Electrolyte solutions. London: Butterworths Scientific Publications, 1959.

    Google Scholar 

  2. J. Stuehr and E. Yeager. In: Physical Acoustics / Ed. W. P. Mason. Academic Press: New York. 1965, 2A, C. 6, 351–462.

  3. T. Erdey-Gru. Transport phenomena in aqueous solutions. Academiai Kiado-Budapest, 1974.

  4. V. V. Shcherbakov, Y. M. Artemkina, N. V. Pleshkova, and K. R. Seddon. Russ. J. Electrochem., 2009, 45(8), 922.

    Article  CAS  Google Scholar 

  5. Y. M. Artemkina, V. I. Ermakov, and V. V. Shcherbakov. Usp. Khim. Khim. Tekhnol., 2012, 26(2), 43.

    Google Scholar 

  6. B. I. Laptev, G. N. Sidorenko, N. P. Gorlenko, A. K. Kulchenko, Y. S. Sarkisov, and L. V. Antoshkin. Vestn. Tomsk. Gos. Arkhit.-Stroit. Univ., 2013, (2), 235.

  7. Y. M. Artemkina, N. M. Kuznecov, F. S. Talalaev, and V. V. Scherbakov. Usp. Khim. Khim. Tekhnol., 2013, 27(2), 61.

    Google Scholar 

  8. V. V. Shcherbakov and Y. M. Artemkina. Russ. J. Phys. Chem. A, 2013, 87(6), 1058.

    Article  CAS  Google Scholar 

  9. G. D. Koposov, A. S. Volkov, and A. V. Thunen. Vestn. Sev. (Arkt.) Fed. Univ. Ser.: Estestv. Nauki, 2014, (4), 121.

  10. A. P. Gerdt, I. E. Stas, and H. V. Aksenova. Izv. Altay. Gos. Univ., 2010, (3-2), 141.

  11. A. V. Kobelev, A. K. Lyashchenko, and A. S. Lileev. Rus. J. Inorg. Chem. [Rep.], 2011, 56(4), 652.

    Article  CAS  Google Scholar 

  12. A. V. Kobelev, A. K. Lyashchenko, and A. S. Lileev. Rus. J. Inorg. Chem. [Rep.], 2011, 56(10), 1666.

    Article  CAS  Google Scholar 

  13. A. K. Lyashchenko, A. V. Kovelev, I. M. Karataeva, and A. S. Lileev. Rus. J. Inorg. Chem., 2014, 59(7), 757.

    Article  CAS  Google Scholar 

  14. V. K. Semenchenko. Physical theory of solutions [in Russian]. Gosizdat tekhniko-teoreticheskoy literatury: Moscow-Leningrad, 1941.

    Google Scholar 

  15. H. Mori. Prog. Theor. Phys., 1965, 33(3), 423.

    Article  Google Scholar 

  16. R. Zwanzig and R.D. Mountain. J. Chem. Phys., 1965, 43(12), 4464.

    Article  CAS  Google Scholar 

  17. M. H. Ernst, E. H. Hauge, and M. J. Van Leeuwen. Phys. Rev. Let., 1970, 25(18), 1254.

    Article  Google Scholar 

  18. D. N. Zubarev. Nonequilibrium statistical thermodynamics [in Russian]. Nauka: Moscow, 1971.

    Google Scholar 

  19. I. Z. Fisher. Zh. Eksp. Teor. Fiziki, 1971, 61(4(10)), 1647.

    CAS  Google Scholar 

  20. Y. Pomeau. Phys. Rev. A: Gen. Phys., 1972, 5(6), 2569; 1973, 7(3), 1134.

    Article  Google Scholar 

  21. I. R. Yukhnovsky and M. F. Golovko. Statistical theory of classical equilibrium systems [in Russian]. Naukova dumka: Kiev, 1980.

    Google Scholar 

  22. D. Evans, G. Henli, and Z. Gess. In: Physics Abroad 86. Ser. A: Investigation [in Russian]. Mir, Moscow, 1986, 7–28.

  23. S. Srudhar and P. Taborek. J. Chem. Phys., 1988, 88(2), 1170.

    Article  Google Scholar 

  24. K. Tankeshwar, K. N. Pathak, and S. Ranganathan. J. Condens. Mather., 1990, 2(26), 5891.

    Article  Google Scholar 

  25. S. Odinaev and I. Ojimamadov. Condens. Matter Phys., 2004, 7(4(40)), 735.

    Article  Google Scholar 

  26. S. Odinaev and D. M. Akdodov. Rus. J. Phys. Chem. A, 2013, 87(7), 1129.

    Article  CAS  Google Scholar 

  27. S. Odinaev and D. M. Akdodov. J. Mol. Liq., 2015, 212, 957.

    Article  CAS  Google Scholar 

  28. S. Odinaev and D. M. Akdodov. Rus. J. Phys. Chem. A, 2016, 90(6), 877.

    Article  CAS  Google Scholar 

  29. S. Odinaev and R. S. Makhmadbegov. J. Struct. Chem., 2018, 59(3), 604.

    Article  CAS  Google Scholar 

  30. S. Odinaev and Kh. Idibeg. Rep. Acad. Sci. Repub. Tajikistan [in Russian], 2018, 61(3), 261.

    Google Scholar 

  31. H. Krienke and J. Barthel. Equations of State for Fluids and Fluids Mixtures. Ch. 16: Jonic Fluids / Ed. J. V. Sengers et al. Elsevier: Amsterdam, 2000, 751.

  32. J. Richardi, P. H. Fries, and H. Krienke. J. Chem. Phys., 1998, 108(10), 4079.

    Article  CAS  Google Scholar 

  33. D. Dobos. Electrochemical Data. Handbook for Electrochemists in Industry and Universities, Akademiai Kiado, Budapest, 1975.

    Google Scholar 

  34. N. I. Maksimova, Ch. S. Pak, and N. N. Pravdin, et al. Electrolyte properties [in Russian]. Moscow: Metallurgiya, 1987.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Umarov Physical-Technical Institute, Academy of Sciences of the Republic of Tajikistan, Dushanbe, Tajikistan

    S. Odinaev & Kh. I. Idibegzoda

  2. Tajik National University, Dushanbe, Tajikistan

    D. M. Akdodov

Authors
  1. S. Odinaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Akdodov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kh. I. Idibegzoda
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Odinaev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Odinaev, S., Akdodov, D.M. & Idibegzoda, K.I. Frequency Dispersion of the Specific Conductance Coefficient in Aqueous Electrolyte Solutions. J Struct Chem 60, 434–442 (2019). https://doi.org/10.1134/S0022476619030119

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476619030119

Keywords

Search

Navigation