Abstract
Stable colloidal dispersions with a 2 mM TiS3 concentration (300 mg/l) are obtained by ultrasonic treatment of TiS3 in acetonitrile and isopropyl alcohol and characterized by physicochemical methods. The electrical double layers for the particles in dispersions are estimated from the measured ζ-potentials, and the energies of interparticle interactions are calculated based on the Derjaguin–Landau–Verwey–Overbeek theory. The structural and spectroscopic identity of the particles and crystalline TiS3 is demonstrated for the solid phases obtained from the dispersions.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. N. Coleman, Acc. Chem. Res., 46, No. 1, 14–22 (2013).
V. Nicolosi, M. Chhowalla, M. G. Kanatzidis, et al., Science, 340, 1226419 (2013).
V. E. Fedorov, Chalcogenides of High-Melting Transition Metals. Quasi-One-Dimensional Compounds [in Russian], Nauka, Novosibirsk (1988).
L. Brattas and A. Kjekshus, Acta Chem. Scandin., 26, No. 9, 3441–3449 (1972).
S. Furuseth, L. Brattas, and A. Kjekshus, Acta Chem. Scandin., A29, No. 6, 623–631 (1975).
M. Abdulsalam and D. P. Joubert, Phys. Status Solidi B, 253, No. 5, 868–874 (2016).
I. J. Ferrer, J. R. Ares, J. M. Clamagirand, et al., Thin Solid Films, 535, 398–401 (2013).
J. Island, R. Biele, M. Barawi, et al., Sci. Rep., 6, 22214 (2016).
F. Xia, H. Wang, and Y. Jia, Nature Commun., 5, 4458 (2014).
M. Barawi, E. Flores, I. J. Ferrer, et al., J. Mater. Chem. A, 3, No. 15, 7959–7965 (2015).
S. B. Artemkina, T. Y. Podlipskaya, A. I. Bulavchenko, et al., Colloids and Surfaces A: Physicochem. Engineer. Aspects, 461, 30–39 (2014).
V. E. Fedorov, S. B. Artemkina, N. G. Naumov, et al., J. Mater. Chem. C, 2, No. 28, 5479–5486 (2014).
P. A. Poltorak, S. B. Artemkina, A. I. Bulavchenko, et al., Russ. Chem. Bull., 64, No. 8, 1850–1856 (2015).
G. D. J. Phillies, Analyt. Chem., 62, No. 20, 1049–1057 (1990).
P. Gard, F. Cruege, C. Sourisseau, and O. Gorochov, J. Raman Spectrosc., 17, 283–288 (1986).
B. V. Derjaguin, N. V. Churaev, and V. M. Muller, The Derjaguin Landau Verwey Overbeek (DLVO) Theory of Stability of Lyophobic Colloids, Springer, New York (1987), pp. 293–310.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2017 I. P. A. Poltarak, A. A. Poltarak, S. B. Artemkina, T. Yu. Podlipskaya, V. E. Fedorov.
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 5, pp. 1072–1077, June–July, 2017.
Rights and permissions
About this article
Cite this article
Poltarak, P.A., Poltarak, A.A., Artemkina, S.B. et al. Preparation and properties of titanium trisulfide nanoparticles. J Struct Chem 58, 1033–1038 (2017). https://doi.org/10.1134/S0022476617050250
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617050250