Abstract
The crystallogenesis of three groups of structures of fluoride-orthoborates (and their analogs) with large cations is studied from the point of view of the current cation-framework representations. Their cation frameworks are sterically templated by rigid borate anions and are built as antizeolite structures. Cavities of channel or layered types are filled with components different their composition and configuration with the main function as charge compensators. An example of different functionalities of the identical anions are Ba3(BO3)2 and La3Ca3(BO3)5 structures. In these structures, two (BO3) types generate a cation framework, and the third type stabilizes it in ready channels (!).
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
V. A. Blatov, Struct. Bonding, 138, 31–66 (2011).
S. V. Rashchenko, T. B. Bekker, V. V. Bakakin, et al., Cryst. Growth Des., 12, No. 6, 2955–2960 (2012).
S. V. Rashchenko, T. B. Bekker, V. V. Bakakin, et al., J. Appl. Crystallogr., 46, 1081–1084 (2013).
P. N. Gavryushkin, V. V. Bakakin, N. B. Bolotina, et al., Cryst. Growth Des., 14, 4610–4616 (2014).
T. B. Bekker, S. V. Rashchenko, V. V. Bakakin, et al., CrystEngComm., 14, 6910–6915 (2012).
S. V. Rashchenko, V. V. Bakakin, S. G. Kozlova, et al., J. Struct. Chem., 56, No. 1, 85–91 (2015).
P. N. Gavryushkin, V. G. Thomas, N. B. Bolotina, et al., Cryst. Growth Des., 16, 1893–1902 (2016).
S. V. Rashchenko, T. B. Bekker, V. V. Bakakin, et al., J. Alloys Compd., 694, 1196–1200 (2017).
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, Russ. Chem. Rev., 84, No. 4, 393–421 (2015).
V. V. Bakakin and Yu. V. Seryotkin, J. Struct. Chem., 57, No. 4, 698–703 (2016).
X. Lin, F. Zhang, S. Pan, et al., J. Mater. Chem. C, 2, 4257–4264 (2014).
S. Schmid, J. Senker, and W. Schnick, J. Solid State Chem., 174, 221–228 (2003).
C. Liu, H. Liang, X. Kuang, J. Zhong, et al., Inorg. Chem., 51, No. 16, 8802–8809 (2012).
G. Zou, N. Ye, L. Huang, and X. Lin, J. Am. Chem. Soc., 133, No. 49, 20001–20007 (2011).
Yu. E. Gorbunova, D. G. Detkov, and Yu. V. Kokunov, Russ. J. Inorg. Chem., 49, No. 9, 1359–1362 (2004).
H. Krueger, Z. Kristallogr., 225, 418–424 (2010).
J. Zhao and R. K. Li, Inorg. Chem., 53, 2501–2505 (2014).
L. Dong, S. Pan, Z. Yang, et al., Z. Anorg. Allg. Chem., 638, No. 14, 2280–2285 (2012).
B. Aurivillius, Chem. Scr., 22, 168–170 (1983).
W. Zhao, S. Pan, X. Dong, et al., Mater. Res. Bull., 47, 947–951 (2012).
L. Dong, S. Pan, H. Wu, et al., J. Solid State Chem., 204, 64–69 (2013).
J. Li, S. Pan, W. Zhao, et al., Solid State Sci., 13, 966–969 (2011).
X. Chen, F. Song, X. Chang, et al., J. Solid State Chem., 182,. 3091–3097 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2017 V. V. Bakakin.
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 5, pp. 986–991, June–July, 2017.
Rights and permissions
About this article
Cite this article
Bakakin, V.V. On a dual function of anions in crystallogenesis of compounds: Structure-directing and stabilizing. J Struct Chem 58, 947–952 (2017). https://doi.org/10.1134/S0022476617050134
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617050134