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Crystal structure and 121,123Sb NQR parameters of ammonium tridecafluorotetraantimonate(III) NH4Sb4F13

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Abstract

(NH4)Sb4F13 crystals (I) are synthesized and their crystal structure (tetragonal crystal system: a = 9.6431(2) Å, c = 6.5503(2) Å, V = 609.11(3) Å3, Z = 2, d calc = 4.100 g/cm3, F(000) = 664, space group I4̅) is determined. The main structural units of I are tetranuclear anionic [Sb4F13]− complexes and [NH4]+ cations. The anionic complexes are built of four SbF3 groups linked together by tetrahedral bridging fluorine atom. At room temperature the (NH4)Sb4F13 crystals are isostructural to previously studied МSb4F13 (М = K, Rb, Cs, and Tl). The study of 121,123Sb NQR spectra of compound I is performed in a range of 77-370 K, which shows that when the temperature decreases (<250 K) the substance exhibits piezoelectric properties, as do other compounds of this group, but with a violation of their isostructurality.

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References

  1. L. A. Zemnukhova, Synthesis, NQR Spectroscopy, and Structure of the Coordination Compounds of Antimony(III), Bismuth(III), Indium(III), and Tellurium(IV): Diss. … Dr. of Chem. Sc. [in Russian], Inst. of Chemistry, Far Eastern Branch, RAS, Vladivostok (1998).

    Google Scholar 

  2. V. Ya. Kavun, V. I. Sergienko, Diffusion Mobility and Ionic Transport in Crystalline and Amorphous Fluorides of the Group 4 Elements and Antimony(III) [in Russian], Dalnauka, Vladivostok (2004).

    Google Scholar 

  3. E. V. Kovaleva, L. A. Zemnukhova, V. M. Nikitin, M. D. Koryakova, and N. V. Speshneva, Russ. J. Appl. Chem., 75, No. 6, 971 (2002).

    Article  Google Scholar 

  4. B. Ducourant, R. Fourcade, and G. Masherpa, Rev. Chim. Min., 20, No. 3, 314 (1983).

    CAS  Google Scholar 

  5. A. A. Udovenko, L. A. Zemnukhova, Yu. E. Gorbunova, Yu. N. Mikhailov, and R. L. Davidovich, Rus. J. Coord. Chem., 28, No. 1, 14 (2002).

    Article  Google Scholar 

  6. A. A. Udovenko, Yu. E. Gorbunova, L. A. Zemnukhova, Yu. N. Mikhailov, and R. L. Davidovich, Rus. J. Coord. Chem., 27, No. 7, 514 (2001).

    Article  Google Scholar 

  7. V. E. Ovchinnikov, A. A. Udovenko, L. P. Solovieva, L. M. Volkova, and R. L. Davidovich, Koord. Khim., 8, No. 5, 697 (1982).

    CAS  Google Scholar 

  8. A. A. Udovenko, L. M. Volkova, P. S. Gordienko, R. L. Davidovich, M. Yu. Antipin, and Yu. T. Struchkov, Koord. Khim., 13, No. 4, 558 (1987).

    CAS  Google Scholar 

  9. D. Tichit, B. Ducourant, R. Fourcade, and G. Mascherpa, J. Fluor. Chem., 13, No. 1, 45 (1979).

    Article  Google Scholar 

  10. B. Ducourant, R. Fourcade, E. Philippot, and G. Mascherpa, Rev. Chim. Min., 12, No. 6, 553 (1975).

    CAS  Google Scholar 

  11. A. A. Udovenko, L. A. Zemnukhova, Yu. E. Gorbunova, Yu. N. Mikhailov, and R. L. Davidovich, Rus. J. Coord. Chem., 29, No. 5, 334 (2003).

    Article  Google Scholar 

  12. A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva, and G. A. Fedorishcheva, Rus. J. Coord. Chem., 30, No. 9, 656 (2004).

    Article  Google Scholar 

  13. V. Ya. Kavun, N. F. Uvarov, L. A. Zemnukhova, and O. V. Brovkina, Russ. J. Inorg. Chem., 49, No. 6, 1012 (2004).

    CAS  Google Scholar 

  14. L. M. Avkhutskii, R. L. Davidovich, L. A. Zemnukhova, P. S. Gordienko, V. Urbonavicius, and J. Grigas, Phys. Stat. Sol. (b), 116, 483 (1983).

    Article  CAS  Google Scholar 

  15. L. A. Zemnukhova and R. L. Davidovich, Z. Naturforsch., 53a, 573 (1998).

    Google Scholar 

  16. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the Smart System. Bruker AXS Inc. Madison (WI, USA) (1998).

  17. G. M. Sheldrick, SHELXTL/PC. Versions 5.0. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data. Bruker AXS Inc. Madison, (WI, USA) (1998).

    Google Scholar 

  18. A. A. Udovenko and L. M. Volkova, Koord. Khim., 7, No. 12, 1763 (1981).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia

    L. A. Zemnukhova, A. A. Udovenko & N. V. Makarenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    S. I. Kuznetsov & T. A. Babushkina

Authors
  1. L. A. Zemnukhova
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  2. A. A. Udovenko
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  3. N. V. Makarenko
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  4. S. I. Kuznetsov
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  5. T. A. Babushkina
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Correspondence to N. V. Makarenko.

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Original Russian Text © 2017 L. A. Zemnukhova, A. A. Udovenko, N. V. Makarenko, S. I. Kuznetsov, T. A. Babushkina.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 4, pp. 729–733, July–August, 2017.

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Zemnukhova, L.A., Udovenko, A.A., Makarenko, N.V. et al. Crystal structure and 121,123Sb NQR parameters of ammonium tridecafluorotetraantimonate(III) NH4Sb4F13 . J Struct Chem 58, 694–699 (2017). https://doi.org/10.1134/S0022476617040072

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  • DOI: https://doi.org/10.1134/S0022476617040072

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