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Characterization, luminescent properties, crystal structure determination, and thermal properties of [Tl(Ph2phen)Cl3(DMSO)]

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Abstract

The new mixed-ligand complex of [Tl(Ph2phen)Cl3(DMSO)] (1) is obtained from the reaction of TlCl3∙4H2O with 4,7-diphenyl-1,10-phenanthroline (Ph2phen) in a methanol solution. Suitable crystals of 1 are obtained for the X-ray diffraction measurement by methanol diffusion into a DMSO solution. This complex is characterized by spectral methods (IR, UV-Vis, 1H NMR, and luminescence), elemental analysis, thermal analysis (TG, DTA), and single crystal X-ray diffraction.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    M. Ghadermazi

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  1. M. Ghadermazi
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Correspondence to M. Ghadermazi.

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The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 1020-1025, June-July, 2016.

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Ghadermazi, M. Characterization, luminescent properties, crystal structure determination, and thermal properties of [Tl(Ph2phen)Cl3(DMSO)]. J Struct Chem 57, 970–975 (2016). https://doi.org/10.1134/S0022476616050176

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  • DOI: https://doi.org/10.1134/S0022476616050176

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