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Crystal structures and characterization of two rare-earth-glutarate coordination networks: One-dimensional [Nd(C5H6O4)(H2O)4]•Cl and three-dimensional [Pr(C5H6O4)(C5H7O4)(H2O)]•H2O

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Abstract

The synthesis, crystal structures, and characterization (IR, TGA/DSC) of [Nd(C5H6O4)(H2O)4]•Cl (1) and [Pr(C5H6O4)(C5H7O4)(H2O)]•H2O (2) are described. Compound 1 is a one-dimensional coordination polymer containing double chains incorporating pairs of edge-sharing NdO9 polyhedra linked by glutarate dianions. A network of O–H…O and O–H…Cl hydrogen bonds helps to consolidate the structure. Compound 2 is a three-dimensional coordination polymer incorporating chains of edge-sharing PrO10 polyhedra. Its glutarate ion adopts an extended conformation, whereas its hydrogen glutarate ion takes on a twisted conformation. O–H…O hydrogen bonds are seen in the crystal structure, which features small channels occupied by water molecules. Crystal data: 1, C5H14ClNdO8, M r = 381.85, monoclinic, P21/c (No. 14), a = 8.9763(6) Å, b = 15.9277(11) Å, c = 8.8690(6) Å, β = 112.090(2)°, V = 1174.94(14) Å3, Z = 4, R(F) = 0.016, wR(F 2) = 0.037. 2, C10H17O10Pr, M r = 438.15, orthorhombic, Pbca (No. 61), a = 16.3030(7) Å, b = 8.6714(4) Å, c = 19.3899(8) Å, V = 2741.1(2) Å3, Z = 8, R(F) = 0.020, wR(F 2) = 0.050.

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Authors and Affiliations

  1. Department of Chemistry, Government College University, Lahore, Pakistan

    S. Hussain & I. U. Khan

  2. Department of Chemistry, University of Aberdeen, Aberdeen, Scotland

    W. T. A. Harrison

  3. Department of Physics, University of Sargodha, Sargodha, Pakistan

    M. N. Tahir

Authors
  1. S. Hussain
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  2. I. U. Khan
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  3. W. T. A. Harrison
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  4. M. N. Tahir
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Correspondence to S. Hussain or W. T. A. Harrison.

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Original Russian Text © 2015 S. Hussain, I. U. Khan, W. T. A. Harrison, M. N. Tahir.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 5, pp. 993–1000, September–October, 2015.

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Hussain, S., Khan, I.U., Harrison, W.T.A. et al. Crystal structures and characterization of two rare-earth-glutarate coordination networks: One-dimensional [Nd(C5H6O4)(H2O)4]•Cl and three-dimensional [Pr(C5H6O4)(C5H7O4)(H2O)]•H2O. J Struct Chem 56, 934–941 (2015). https://doi.org/10.1134/S0022476615050169

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