Abstract
A crystallographic analysis of ellisite Tl3AsS3, fangite Tl3AsS4, lorandite TlAsS2, and synthetic Tl3AsS3 shows that the configuration of atomic positions in these structures is determined mostly by the ordering of S2– anions and the large massive Tl+ cations in a single packing. The standard coordination of the As cation is provided only by the strong covalent As–S bonds; the environment of Tl+ cations varies depending on the geometry of their packing with sulfur.
Similar content being viewed by others
References
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, J. Struct. Chem., 55, No. 5, 863–870 (2014).
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, Kristallografiya, 56, No. 6, 1001–1006 (2011).
S. V. Borisov, N. V. Pervukhina, and S. A. Magarill, J. Struct. Chem., 55, No. 1, 77–83 (2014).
M. Gostojic, Z. Kristallogr., 151, No. 3/4, 249–254 (1980).
S. A. Gromilov, E. A. Bykova, and S. V. Borisov, Kristallografiya, 56, 1013–1018 (2011).
J. R. Wilson, P. K. S. Gupta, P. D. Robinson, and A. J. Criddle, Am. Mineral., 78, 1096–1103 (1993).
M. E. Fleet, Z. Kristallogr., 138, 147–160 (1973).
Z.-M. Yang and F. Pertlik,J. Alloys Compd., 216, 155–158 (1994).
S. V. Borisov, S. A. Magarill, N. V. Podberezskaya, and N. V. Pervukhina, J. Struct. Chem., 38, No. 5, 759–764 (1997).
S. V. Borisov, N. V. Podberezskaya, N. V. Pervukhina, and S. A Magarill, Z. Kristallogr., 213, 253–258 (1998).
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, Algorithms and Practice of Crystallographic Analysis of Atomic Structures [in Russian], SO RAs, Novosibirsk (2012).
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, J. Struct. Chem., 52, No. 3, 517–523 (2011).
S. V. Borisov, S. A. Magarill, and N. V. Pervukhina, J. Struct. Chem., 54, No. 5, 963–967 (2013).
S. V. Borisov, N. V. Pervukhina, and S. A. Magarill, J. Struct. Chem., 54, No. 6, 1070–1076 (2013).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 4, pp. 728-737, July-August, 2015. Original article submitted March 12, 2014.
Rights and permissions
About this article
Cite this article
Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. Crystallographic analysis and features of cation coordination in a series of structures of sulfides with Tl+ . J Struct Chem 56, 680–688 (2015). https://doi.org/10.1134/S0022476615040113
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476615040113