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Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion

  • Self-Organization in Molecular and Supramolecular Compounds
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Abstract

Two new polyoxovanadoborates based crystalline lattices are being reported: K5(H3O)2(1,3-diapH2)2[V12B18O60H6]·10.80H2O (1), and K2(H3O)7(enH2)[V12B18O60H6]·9H2O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2) and hydronium ions, and the oxygen atoms of the [V12B18O60H6] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12B18O60H6] anionic cluster for (1) and (2) being 11/1 (VIV/VV) ratio.

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Authors and Affiliations

  1. Facultad de Química y Biología, Universidad de Santiago de Chile, USACH, Santiago, Chile

    P. Hermosilla-Ibáñez, J. Costamagna & D. Venegas-Yazigi

  2. CEDENNA, Santiago, Chile

    P. Hermosilla-Ibáñez, A. Vega, V. Paredes-García, E. Spodine & D. Venegas-Yazigi

  3. Departamento de Ciencias Químicas, Facultad de Ciencias Exactas, Universidad Andres Bello, Santiago, Chile

    A. Vega & V. Paredes-García

  4. Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Santiago, Chile

    M. T. Garland

  5. ENSCR, CNRS, UMR 6226, Rennes, France

    E. Le Fur

  6. Université Européenne de Bretagne, Rennes, France

    E. Le Fur

  7. Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Santiago, Chile

    E. Spodine

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  1. P. Hermosilla-Ibáñez
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  2. J. Costamagna
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  3. A. Vega
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  4. V. Paredes-García
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  6. E. Le Fur
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  8. D. Venegas-Yazigi
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Correspondence to D. Venegas-Yazigi.

Additional information

Original Russian Text © 2014 P. Hermosilla-Ibáñez, J. Costamagna, A. Vega, V. Paredes-García, M. T. Garland, E. Le Fur, E. Spodine, D. Venegas-Yazigi.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, Supplement 2, pp. S279–S290, 2014.

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Hermosilla-Ibáñez, P., Costamagna, J., Vega, A. et al. Protonated diamines as linkers in the supramolecular assemblies based on the [V12B18O60H6] polyoxovanadoborate anion. J Struct Chem 55, 1453–1465 (2014). https://doi.org/10.1134/S0022476614080125

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  • DOI: https://doi.org/10.1134/S0022476614080125

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