Abstract
Trigonal pyramidal oxyanions, EO 2−3 (E = S, Se, Te), were utilized as a template in the formation of Ag16 clusters, which dimerize via intermolecular Ag-S bonds to form a Ag32 cluster stabilized by 1,1-dithiolate ligands. Structural elucidations on [Ag16(EO3){S2P(OEt)2}12]2+ in comparison with tetrahedral oxyanioncentered Ag16 clusters previously characterized from this group clearly suggest that the lone-pair electrons on chalcogen center has a structure-directing effect.
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Original Russian Text © 2014 H.-W. Chang, J.-H. Liao, B. Li, Y.-J. Chen, C. W. Liu.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, Supplement 2, pp. S253–S259, 2014.
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Chang, H.W., Liao, J.H., Li, B. et al. Trigonal pyramidal oxyanions as structure-directing templates for the synthesis of silver dithiolate clusters. J Struct Chem 55, 1426–1432 (2014). https://doi.org/10.1134/S0022476614080071
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DOI: https://doi.org/10.1134/S0022476614080071