Skip to main content
SpringerLink
Log in

Negative differential resistance in polyoxometalates

  • Miscellaneous
  • Published:
JETP Letters Aims and scope Submit manuscript

Abstract

Large-scale (with peak-to-valley ratios up to 100) controllable multiple negative differential resistances have been revealed in tunneling spectra of one of the polyoxometalates (ammonium decamolybdodicobaltate(III)) in experiments with a scanning tunneling microscope in air under normal conditions and standard humidity. Conditions necessary for the observation of such negative differential resistances have been determined. A mechanism of their formation common for all nanostructures with weak intramolecular bonds has been revealed. A strategy for the selection of materials for molecular electronics based on the optimization of the composition and architecture of metal oxides has been proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Song, M. Reed, and T. Lee, Adv. Mater. 23, 1583 (2011).

    Article  Google Scholar 

  2. J. C. Cuevas and E. Scheer, Molecular Electronics: An Introduction to Theory and Experiment (Nanotechnology and Nanoscience), World Scientific Series in Nanotechnology and Nanoscience (World Scientific, Singapore, 2010), Vol. 1.

    Book  Google Scholar 

  3. C. I. Cabello, M. Franco, F. M. Cabrerizo, A. Alvarez, and H. J. Thomas, J. Mol. Catal. Chem. 186, 89 (2002).

    Article  Google Scholar 

  4. C. Martin, C. Lamonier, M. Fournier, M. O. Olivier, V. Harlé, D. Guillaume, and E. Payen, Chem. Mater. 17, 4438 (2005).

    Article  MATH  Google Scholar 

  5. J. Chen, W. Wang, M. A. Reed, A. M. Rawlett, D. W. Price, and J. M. Tour, Appl. Phys. Lett. 77, 1224 (2000).

    Article  ADS  Google Scholar 

  6. D. M.-T. Kuo and Y.-C. Chang, Phys. E: Low-Dim. Syst. Nanostruct. 41, 395 (2009).

    Article  ADS  Google Scholar 

  7. I. Kratochvilova, M. Kocirik, A. Zambova, J. Mbindyo, T. E. Mallouk, and T. S. Mayer, J. Mater. Chem. 12, 2927 (2002).

    Article  Google Scholar 

  8. F. I. Dalidchik, S. A. Kovalevskii, and B. A. Budanov, Nanotechnol. Russ. 7, 635 (2012).

    Article  Google Scholar 

  9. I. K. Song and M. A. Barteau, Langmuir 20, 1850 (2004).

    Article  Google Scholar 

  10. I. K. Song, M. S. Kaba, and M. A. Barteau, J. Phys. Chem. 100, 17528 (1996).

    Article  Google Scholar 

  11. I. K. Song, M. S. Kaba, and M. A. Barteau, J. Phys. Chem. 100, 19577 (1996).

    Article  Google Scholar 

  12. I. K. Song, J. R. Kitchin, and M. A. Barteau, Proc. Natl. Acad. Sci. 99, 6471 (2002).

    Article  ADS  Google Scholar 

  13. M. Kinne and M. A. Barteau, Surf. Sci. 447, 105 (2000).

    Article  ADS  Google Scholar 

  14. I. K. Song, J. E. Lyons, and M. A. Barteau, Catal. Today 81, 137 (2003).

    Article  MATH  Google Scholar 

  15. I. K. Song, M. S. Kaba, and M. A. Barteau, Langmuir 18, 2358 (2002).

    Article  Google Scholar 

  16. I. K. Song, personal communication.

  17. J. Freund, J. Halbritter, and J. K. H. Horber, Microsc. Res. Tech. 44, 327 (1999).

    Article  Google Scholar 

  18. S. Yu. Vasil’ev and A. V. Denisov, Tech. Phys. 45, 99 (2000).

    Article  Google Scholar 

  19. F. I. Dalidchik, E. M. Balashov, B. A. Budanov, A. K. Gatin, M. V. Grishin, A. A. Kirsankin, S. A. Kovalevskii, N. N. Kolchenko, V. G. Slutskii, and B. R. Shub, Russ. J. Phys. Chem. B 4, 896 (2010).

    Article  Google Scholar 

  20. F. I. Dalidchik, B. A. Budanov, N. N. Kolchenko, E. M. Balashov, and S. A. Kovalevskii, J. Exp. Theor. Phys. 115, 1068 (2012).

    Article  ADS  Google Scholar 

  21. F. I. Dalidchik, S. A. Kovalevskii, E. M. Balashov, and B. A. Budanov, Kinet. Catal. 53, 610 (2012).

    Article  Google Scholar 

  22. J. J. Davis, N. Wang, A. Morgan, T. Zhang, and J. Zhao, Faraday Discuss 131, 167 (2006).

    Article  ADS  Google Scholar 

  23. W. Lyo and P. Avouris, Science 245, 1369 (1989).

    Article  ADS  Google Scholar 

  24. A. Zazumov, D. Femberg, and T. Martin, Phys. Rev. B 73, 115405 (1006).

    Article  Google Scholar 

  25. M. Globis, A. Wschowiak, R. Yamachika, and M. F. Crommie, Appl. Phys. Lett. 86, 204102 (2005).

    Article  ADS  Google Scholar 

  26. I. Kratochilova, M. Kocirik, A. Zambova, J. Mbindyo, T. E. Mallouk, and T. Mayer, J. Mater. Chem. 12, 2927 (2002).

    Article  Google Scholar 

  27. G. H. Wannier, Rev. Mod. Phys. 34, 645 (1962).

    Article  MathSciNet  ADS  Google Scholar 

  28. F. I. Dalidchik and V. Z. Slonim, Sov. Phys. JETP 43, 25 (1976).

    ADS  Google Scholar 

  29. E. G. Petrov, J. Low Temp. Phys. 31, 338 (2005).

    Article  Google Scholar 

  30. J. C. Cuevas, J. Heurich, F. Pauly, W. Wenzel, and G. Schon, Nanotechnology 14, R29 (2003).

    Article  ADS  MATH  Google Scholar 

  31. N. Néel, J. Kröger, R. Berndt, and E. Pehlke, Phys. Rev. B 78, 233402 (2008).

    Article  ADS  Google Scholar 

  32. S. A. Kovalevskii, F. I. Dalidchik, G. V. Nizova, and E. M. Balashov, Soft Nanosci. Lett. 4, 24 (2014).

    Article  Google Scholar 

  33. A. G. Boulay, G. J. T. Cooper, and L. Cronin, Polyoxometal. Chem.: Some Recent Trends 8, 101 (2013).

    Google Scholar 

  34. H. N. Miras, J. Yan, D.-L. Long, and L. Cronin, Chem. Soc. Rev. 41, 7403 (2012).

    Article  Google Scholar 

  35. Sh. Wen, G. Yang, L. Yan, H. Li, and Zh. Su, Chem. Phys. Chem. 14, 610 (2013).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    E. M. Balashov, B. A. Budanov, F. I. Dalidchik & S. A. Kovalevskiy

Authors
  1. E. M. Balashov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. A. Budanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. I. Dalidchik
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Kovalevskiy
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. M. Balashov.

Additional information

Original Russian Text © E.M. Balashov, B.A. Budanov, F.I. Dalidchik, S.A. Kovalevskiy, 2015, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2015, Vol. 101, No. 9, pp. 717–722.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Balashov, E.M., Budanov, B.A., Dalidchik, F.I. et al. Negative differential resistance in polyoxometalates. Jetp Lett. 101, 643–647 (2015). https://doi.org/10.1134/S0021364015090052

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0021364015090052

Keywords

Search

Navigation