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Modeling of the Bi2O3·SiO2 Melt Cooling Process and the Products of Melt Solidification under Various Conditions

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Inorganic Materials Aims and scope

Abstract—

Cooling of a melt with the composition Bi2O3·SiO2 and the metastable phase Bi2SiO5 under various conditions has been studied by computer simulation with ProCAST software. Using previously reported thermophysical characteristics (thermal conductivity, heat capacity, and density) of the melt and metastable phase and the experimentally determined thermal diffusivity of the metastable Bi2SiO5 compound in the range 299–700°C, we have evaluated the cooling rate, which has been shown to agree well with the experimentally determined one, confirming that the assumptions made in our simulations are quite adequate.

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ACKNOWLEDGMENTS

In this study, we used equipment at the Krasnoyarsk Krai Shared Research Facilities Center, Krasnoyarsk Scientific Center (Federal Research Center), Siberian Branch, Russian Academy of Sciences.

We acknowledge the use of equipment at the Knowledge Intensive Methods for Characterization and Analysis of Novel Materials, Nanomaterials, and Mineral Raw Materials Shared Research Facilities Center, Siberian Federal University federal state autonomous educational institution of higher education.

Funding

This work was supported by the Russian Federation Ministry of Science and Higher Education (state research target, research theme no. FSRZ-2020-0013).

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Authors and Affiliations

  1. Siberian Federal University, 660041, Krasnoyarsk, Russia

    T. V. Bermeshev, V. P. Zhereb, M. P. Bundin, A. N. Zaloga, A. S. Yasinsky, O. V. Yushkova, D. S. Voroshilov, E. Yu. Podshibyakina, I. Yu. Gubanov & O. V. Yakivyuk

  2. Reshetnev Siberian State University of Science and Technology, 660037, Krasnoyarsk, Russia

    V. P. Zhereb

  3. IME, Institute for Process Metallurgy and Metal Recycling, RWTH Aachen University, 52056, Aachen, Germany

    A. S. Yasinsky

  4. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    E. V. Mazurova

  5. OOO Krasnoyarsk Boiler Plant, 660013, Krasnoyarsk, Russia

    A. B. Nabiulin

  6. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    V. P. Chentsov & V. V. Ryabov

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  1. T. V. Bermeshev
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  2. V. P. Zhereb
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  3. M. P. Bundin
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  4. A. N. Zaloga
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  6. O. V. Yushkova
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  7. D. S. Voroshilov
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  8. E. Yu. Podshibyakina
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  9. I. Yu. Gubanov
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  10. E. V. Mazurova
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  11. A. B. Nabiulin
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  12. V. P. Chentsov
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  14. O. V. Yakivyuk
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Correspondence to T. V. Bermeshev.

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Translated by O. Tsarev

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Bermeshev, T.V., Zhereb, V.P., Bundin, M.P. et al. Modeling of the Bi2O3·SiO2 Melt Cooling Process and the Products of Melt Solidification under Various Conditions. Inorg Mater 58, 1058–1064 (2022). https://doi.org/10.1134/S0020168522100028

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