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General Aspects of the Combustion Synthesis of a Cobalt Alloy with Dispersion and Precipitation Modification

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Abstract—

We have studied the potentialities of dispersion and precipitation modification of a cobalt alloy in combustion mode under the effect of centrifugal forces. The starting mixture consisted of Co3O4, Cr2O3, Nb2O5, MoO3, and Al, with titanium carbide and a mechanical mixture of titanium powder and carbon black as modifying additives. The basic mixture has been shown to burn in a wide range of titanium carbide additions under normal conditions. The use of a centrifugal force field allows the phase separation limit to be increased from 17.5 to 20% titanium carbide. In the case of precipitation modification, the system has greater potential for both combustion and phase separation, and the structural constituents of the alloy are characterized by a smaller size and finer structure. We have proposed a sequence of chemical reactions involved in the modification by the precipitation mechanism, in which Co3O4 decomposition and subsequent release of active oxygen play a key role.

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REFERENCES

  1. Rabadia, C.D., Liu, Y.J., Chen, L.Y., Jawed, S.F., Wang, L.Q., Sun, H., and Zhang, L.C., Deformation and strength characteristics of Laves phases in titanium alloys, Mater. Des., 2019, vol. 179, paper 107891.https://doi.org/10.1016/j.matdes.2019.107891

  2. Gorshkov, V.A., Miloserdov, P.A., Luginina, M.A., Sachkova, N.V., and Belikova, A.F., High-temperature synthesis of a cast material with a maximum content of the MAX phase Cr2AlC, Inorg. Mater., 2017, vol. 53, no. 3, pp. 271–277.https://doi.org/10.1134/S0020168517030062

    Article  CAS  Google Scholar 

  3. Lovshenko, F.G. and Lovshenko, G.F., Criteria for choosing alloying components and basic compositions for the fabrication of mechanically doped metal-based dispersion-hardened materials, Nauka Tekh., 2016, vol. 15, no. 3, pp. 173–182. https://doi.org/https://doi.org/10.21122/2227-1031-2016-15-3-173-182

  4. Anikeev, A.N., Bigeev, A.V., Gordeev, E.N., Chumanov, V.I., and Chumanov, I.V., On the feasibility of introducing solid refractory particles in the fabrication of a pipe billet by spin casting, Vestn. Yuzhno-Uralsk. Gos. Univ., Ser.: Metall., 2009, no. 39 (169), pp. 24–27.

  5. Portnoi, K.I. and Babich, B.N., Dispersnouprochnennye materialy (Dispersion-Hardened Materials), Moscow: Metallurgiya, 1974.

  6. Orowan, E., Condition for dislocation passage of precipitation, Proc. Symp. on Internal Stresses in Metals, 1948, pp. 451–454.

  7. Reed, R.C., The Superalloys Fundamentals and Applications, New York: Cambridge Univ. Press, 2008.

    Google Scholar 

  8. Grigor’ev, S.N., Tarasova, T.V., and Nazarov, A.P., Effect of heat treatment on the structure, phase composition, and properties of high-temperature cobalt alloys prepared by selective laser melting, Perspekt. Mater., 2014, no. 7, pp. 73–80.

  9. Davydov, D.I., Kazantseva, N.V., Ezhov, I.V., and Popov, N.A., Structural phase transformations of high-temperature cobalt alloys, Mezhdunarodnyi mezhdistsiplinarnyi simpozium “Ierarkhicheskie materialy: razrabotka prilozheniya dlya novykh tekhnologii i nadezhnykh konstruktsii” (Int. Interdisciplinary Symp. Hierarchical Materials: Development of Application to Advanced Technologies and Reliable Structures), 2020, pp. 253–254.

  10. Sato, J., Omori, T., Oikawa, K., Ohnuma, I., Kainuma, R., and Ishida, K., Cobalt-base high-temperature alloys, Science, 2006, vol. 7, pp. 90–91.

    Article  Google Scholar 

  11. Shiryaev, A.A., Int. J. Self-Propag. High-Temp. Synth., 1995, vol. 4, no. 4, pp. 351–355.

    CAS  Google Scholar 

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Funding

This work was supported by the Russian Foundation for Basic Research, project no. 19-03-00088.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    K. V. Zakharov, D. E. Andreev, V. I. Yukhvid & N. Yu. Khomenko

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  1. K. V. Zakharov
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  2. D. E. Andreev
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  3. V. I. Yukhvid
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  4. N. Yu. Khomenko
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Correspondence to D. E. Andreev.

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Translated by O. Tsarev

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Zakharov, K.V., Andreev, D.E., Yukhvid, V.I. et al. General Aspects of the Combustion Synthesis of a Cobalt Alloy with Dispersion and Precipitation Modification. Inorg Mater 57, 727–732 (2021). https://doi.org/10.1134/S0020168521070165

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  • DOI: https://doi.org/10.1134/S0020168521070165

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