Abstract—
We have studied the effect of doping with Sn (0.004 and 0.008 at %) on the properties of Bridgman-grown single crystals of an n-type Bi2Te1.5Se1.5 solid solution. Thermoelectric power, electrical conductivity, thermal conductivity, and Hall effect measurements in the range 77–400 K have shown that Sn influences the electrical transport properties of the solid solution. Single crystals with the composition Bi1.9996Sn0.0004Te1.5Se1.5 have higher thermoelectric efficiency in the temperature range 300–370 K than does the Sn-free solid solution. Moreover, measurements of thermoelectric power, which is rather sensitive to carrier concentration fluctuations, have demonstrated that the Sn-doped single crystals have highly uniform electrical properties along their length and across this direction.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0020168520060059/MediaObjects/10789_2020_2385_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0020168520060059/MediaObjects/10789_2020_2385_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0020168520060059/MediaObjects/10789_2020_2385_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0020168520060059/MediaObjects/10789_2020_2385_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0020168520060059/MediaObjects/10789_2020_2385_Fig5_HTML.gif)
Similar content being viewed by others
REFERENCES
Kanatzidis, M.G., Structural evolution and homologies for “design” and prediction of solid-state compounds, Acc. Chem. Res., 2005, vol. 38, no. 4, pp. 361–370.
Shelimova, L.E., Karpinskii, O.G., and Zemskov, V.S., Promising thermoelectric materials based on tetradymite-like layered chalcogenides, Perspekt. Mater., 2000, no. 5, pp. 23–32.
Shevel’kov, A.V., Chemical aspects of the fabrication of thermoelectric materials, Usp. Khim., 2008, vol. 77, no. 1, pp. 3–21.https://doi.org/10.1070/RC2008v077n01ABEH003746
Kanatzidis, M.G., The role of solid state chemistry in the discovery of new thermoelectric materials, Semicond. Semimet., 2001, vol. 69, pp. 51–98.
Ivanova, L.R. and Granatkina, Yu.V., Thermoelectric properties of Bi2Te3–Sb2Te3 single crystals in the range 100–700 K, Inorg. Mater., 2000, vol. 36, no. 7, pp. 672–677.
Lyakishev, N.P., Bannykh, O.A., and Rokhlin, L.L., Diagrammy sostoyaniya dvoinykh metallicheskikh sistem (Phase Diagrams of Binary Metallic Systems), Moscow: Mashinostroenie, 1996, vol. 1.
Ivanova, L.D., Granatkina, Yu.V., and Sidorenko, N.A., Doklady VII Mezhgosudarstvennogo seminara “Termoelektriki i ikh primeneniya” (Proc. VII Int. Seminar on Thermoelectrics and Their Applications), St. Petersburg, 2000, pp. 6–11.
Chung, D.-Y., Hogan, T., Schibdler, J., et al., Complex bismuth chalcogenides as thermoelectrics, Proc. XVI Int. Conf. on Thermoelectrics, Danver: IEEE, 1997, pр. 459–462.
Gasenokova, I.V. and Svechnikova, T.E., Dokl. VIII Mezhgosudarstvennogo seminara “Termoelektriki i ikh primeneniya” (Proc. VIII Int. Seminar on Thermoelectrics and Their Applications), St. Petersburg, 2002, pp. 145–150.
Zhitinskaya, M.K., Nemov, S.A., and Svechnikova, T.E., Sn doping of Bi2Te3, Fiz. Tverd. Tela (S.-Peterburg), 1998, vol. 40, no. 8, pp. 1428–1432.
Zhitinskaya, M.K., Nemov, S.A., and Svechnikova, T.E., Improved homogeneity of the electrical properties of Bi2Te3 –xSex doped with Sn, Proc. 6th Eur. Workshop on Thermoelectrics, Freiburg, 2001.
Zhitinskaya, M.K., Nemov, S.A., Svechnikova, T.E., et al., Extraordinary high homogeneity of electrical properties of Bi2Te3 –xSex single crystals, Proc. 18th Int. Conf. on Thermoelectrics, ICT 99, Baltimore, 1999, pp. 185–187.
Zhitinskaya, M.K., Nemov, S.A., Svechnikova, T.E., and Müller, E., Impurity states of tin in Bi2Te3–xSex (x = 0.06, 0.12) solid solutions, Semiconductors, 2004, vol. 38, no. 2, pp. 182–184.
Reinshaus, P., Sussmann, H., Bohni, M., et al., Proc. 2nd Eur. Symp. on Thermoelectric Materials: Techniques and Applications, Dresden, 1994, p. 90.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Gurbanov, G.R., Adygezalova, M.B. Electrical Transport Properties of a Sn-Doped Bi2Te1.5Se1.5 Solid Solution. Inorg Mater 56, 553–556 (2020). https://doi.org/10.1134/S0020168520060059
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168520060059