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Magnetic Properties of FeCr 2 S 4 -Based Solid Solutions in the FeCr 2 S 4 –CdCr 2 S 4 System

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Abstract

We have studied the magnetic properties of Cd1 –xFexCr2S4 solid solutions in the FeCr2S4–CdCr2S4 system in the range 0.6 ≤ x < 1. Measurements were made in the temperature range 5–300 K in static (≤7960 A/m) and ac (10, 100, and 1000 Hz) magnetic fields of 79.60 A/m peak. All of the materials have been shown to exhibit low-temperature magnetic anomalies due to the effect of orbital ordering in FeCr2S4, a basic component, at 10 K.

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ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research (project no. 17-03-01114) and the Presidium of the Russian Academy of Sciences (basic research program no. 35: Scientific Principles of Producing Novel Functional Materials). Part of this work was supported by the Russian Federation Ministry of Education and Science (state research target no. 0088-2014-0003 for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of basic research).

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Correspondence to T. G. Aminov.

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Translated by O. Tsarev

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Aminov, T.G., Shabunina, G.G., Efimov, N.N. et al. Magnetic Properties of FeCr 2 S 4 -Based Solid Solutions in the FeCr 2 S 4 –CdCr 2 S 4 System . Inorg Mater 55, 210–222 (2019). https://doi.org/10.1134/S0020168519030038

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