Abstract
Thin films based on the SiO2–P2O5–СаO and SiO2–P2O5–CaO–TiO2 systems have been grown from film-forming solutions by a sol–gel process. We have studied the physicochemical processes underlying film growth and the phase composition, structure, and biological activity of the materials obtained. The addition of titanium oxide has been shown to improve the biological activity of the materials.
Similar content being viewed by others
References
Sadat-Shojai, M., Khorasani, M., Dinpanah-Khoshdargi, E., and Jamshidi, A., Synthesis methods for nanosized hydroxyapatite in diverse structures, Acta Biomater., 2013, vol. 9, pp. 7591–7621.
Buchilin, N.V. and Stroganova, E.E., Sintered glassceramic materials based on calcium-phosphate glasses, Glass Ceram., 2008, vol. 7, pp. 256–259.
Zhang, J., Liu, W., Schnitzler, V., and Tancret, F., Calcium phosphate cements for bone substitution: chemistry, handling and mechanical properties, Acta Biomater., 2014, vol. 10, pp. 1035–1039.
Barinov, S.M., Biokeramika na osnove fosfatov kal’tsiya (Calcium Phosphate-Based Bioceramics), Moscow: Nauka, 2005.
Putlyaev, V.I., State-of-the-art bioceramic materials, Soros. Obraz. Zh., 2004, vol. 8, pp. 44–50.
Tret’yakov, Yu.D., Vvedenie v khimiyu tverdofaznykh materialov (Introduction to Solid-State Chemistry), Moscow: Nauka, 2006.
Borilo, L.P., Lyutova, E.S., and Spivakova, L.N., Study of biological properties of thin-film materials on the basis of the SiO2–P2O5–CaO system, Key Eng., Mater., 2016, vol. 683, pp. 427–432.
Lei, B., Chen, X., Wang, Y., Zhao, N., Du, C., and Fang, L., Synthesis and bioactive properties of macroporous nanoscale SiO2–CaO–P2O5 bioactive glass, J. Non-Cryst. Solids, 2009, vol. 355, pp. 2678–2681.
Fialko, M.B., Neizotermicheskaya kinetika v termicheskom analize (Nonisothermal Kinetics in Thermal Analysis), Tomsk: Tomsk. Gos. Univ., 1981.
Kokubo, T., Kushitani, H., and Sakka, S., Solutions able to reproduce in vivo surface-structure changes in bioactive glass-ceramic, Biomaterials, 1990, vol. 24, pp. 721–734.
Suikovskaya, N.V., Khimicheskie metody polucheniya tonkikh plenok (Chemical Methods of Thin Film Growth), Leningrad: Khimiya, 1971.
Vereshchagin, V.I., Polifunktsional’nye neorganicheskie materialy na osnove prirodnykh i iskusstvennykh soedinenii (Multifunctional Inorganic Materials Based on Natural and Synthetic Compounds), Tomsk: Tomsk. Gos. Univ., 2002.
Borilo, L.P., Petrovskaya, T.S., and Lyutova, E.S., Synthesis and properties of thin SiO2–P2O5–CaO films, Inorg. Mater., 2014, vol. 50, no. 8, pp. 810–816.
Iler, R., The Chemistry of Silica, New York: Wiley, 1979.
Borilo, L.P. and Lyutova, E.S., Effect of titania additions on the biological properties of silicate materials, Vestn. Tomsk. Gos. Univ., Khim., 2015, no. 2, pp. 101–111.
Greenspan, D.C., Zhong, J.P., and Wheeler, D.L., Bioactivity and biodegradability: method sol–gel derived bioglass in vitro and in vivo, Bioceramics, 1998, vol. 11, pp. 345–348.
Boccaccini, A.R. and Blaker, J.J., Bioactive composite materials for tissue engineering scaffolds, Expert Rev. Med. Devices, 2005, vol. 2, pp. 303–317.
Gnedenkov, S.V., Sharkeev, Yu.P., Sinebryukhov, S.L., Khrisanfova, O.A., Legostaeva, E.V., Zavidnaya, A.G., Puz’, A.V., and Khlusov, I.A., Growth and properties of bioactive coatings on titanium, Perspekt. Mater., 2011, no. 2, pp. 49–59.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.P. Borilo, E.S. Lyutova, 2017, published in Neorganicheskie Materialy, 2017, Vol. 53, No. 4, pp. 396–401.
Rights and permissions
About this article
Cite this article
Borilo, L.P., Lyutova, E.S. Synthesis and properties of bioactive thin-film materials based on the SiO2–P2O5–СаO and SiO2–P2O5–CaO–TiO2 systems. Inorg Mater 53, 400–405 (2017). https://doi.org/10.1134/S0020168517040033
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168517040033