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Behavior of detonation nanodiamond at high pressures and temperatures in the presence of a hydrogen-containing fluid

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Abstract

The recrystallization of detonation nanodiamond in the presence of hydrogen-containing fluids has been studied at pressures from 6 to 8 GPa and temperatures above 1000°C. Electron microscopy and Xray diffraction data demonstrate that, in the presence of a hydrogen-containing fluid, nanocrystalline diamond recrystallizes to micron dimensions. We discuss the mechanism underlying the influence of hydrogencontaining media on the growth of diamond nanocrystals.

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References

  1. Dolmatov, V.Yu., Ul’tradispersnye almazy detonatsionnogo sinteza. Poluchenie, svoistva, primenenie (Detonation Nanodiamond: Preparation, Properties, and Applications), St. Petersburg: SPbGPU, 2003.

    Google Scholar 

  2. Yushin, G.N., Osswald, S., Padalko, V.I., Bogatyreva, G.V., and Gogotsi, Y., Effect of sintering on structure of nanodiamond, Diamond Relat. Mater., 2005, vol. 14, pp. 1721–1729.

    Article  CAS  Google Scholar 

  3. Senyut, V.T. and Mosunov, E.I., Physical–mechanical properties of nanocrystalline materials based on ultrafinedispersed diamonds, Phys. Solid State, 2004, vol. 46, no. 4, pp. 767–769.

    Article  CAS  Google Scholar 

  4. Bochechka, A.A., Properties of polycrystals produced by high-pressure sintering of diamond nanopowders from detonation and static synthesis, Sverkhtverd. Mater., 2002, no. 6, pp. 37–50.

    Google Scholar 

  5. Kidalov, S.V., Shakhov, F.M., Vul, A.Ya., and Ozerin, A.N., Grain-boundary heat conductance in nanodiamond composites, Diamond Relat. Mater., 2010, vol. 19, pp. 976–980.

    Article  CAS  Google Scholar 

  6. Dolmatov, V.Yu., Veretennikova, M.V., Marchukov, V.A., and Sushchev, V.G., Currently available methods of industrial nanodiamond synthesis, Phys. Solid State, 2004, vol. 46, no. 4, pp. 611–615.

    Article  CAS  Google Scholar 

  7. Kulakova, I.I., Surface chemistry of nanodiamonds, Phys. Solid State, 2004, vol. 46, no. 4, pp. 636–643.

    Article  CAS  Google Scholar 

  8. Vityaz, P.A. and Senyut, V.T., Compaction of nanodiamonds produced under detonation conditions and properties of composite and polycrystalline materials made on their basis, Phys. Solid State, 2004, vol. 46, no. 4, pp. 764–766.

    Article  CAS  Google Scholar 

  9. Kulakova, I.I., Gubarevich, T.M., Dolmatov, V.Yu., and Rudenko, A.P., Chemical properties of detonation nanodiamond, Sverkhtverd. Mater., 2000, no. 1, pp. 46–53.

    Google Scholar 

  10. Shul’zhenko, A.A., Bochechka, A.A., Romanko, L.A., Katsai, A.M., and Gargin, V.G., Sintering behavior of diamond nanopowders heat-treated in vacuum, Sverkhtverd. Mater., 2000, no. 6, pp. 50–56.

    Google Scholar 

  11. Davydov, V.A., Rakhmanina, A.V., Rols, S., Agafonov, V., Pulikkathara, M.X., Vander Wal, R.L., and Khabashesku, V.N., Size-dependent phase transition of diamond to graphite at high pressure, J. Phys. Chem., 2007, vol. 111, pp. 12918–12925.

    CAS  Google Scholar 

  12. Voronov, O.A. and Rakhmanina, A.V., Naphthalene carbonization kinetics at 8 GPa, Inorg. Mater., 1992, vol. 28, no. 7, pp. 1408–1413.

    CAS  Google Scholar 

  13. Davydov, V.A., Shiryaev, A.A., Rakhmanina, A.V., Filonenko, V.P., Lypin, S.G., Vasiliev, A.L., Roddatis, V.V., Autret, C., Agafonov, V.N., and Khabashesku, V.N., Transformations of polyhedral carbon nanoparticles under high pressures and temperatures, Carbon, 2011, vol. 49, pp. 2389–2401.

    Article  CAS  Google Scholar 

  14. Khvostantsev, L.G., Slesarev, V.N., and Brazhkin, V.V., Toroid type high-pressure device: history and prospects, High Pressure Res. Int. J., 2004, vol. 24, no. 3, pp. 371–383.

    Article  CAS  Google Scholar 

  15. Mirkin, L.I., Spravochnik po rentgenostrukturnomu analizu polikristallov (X-Ray Diffraction Analysis of Polycrystals: A Handbook), Moscow: Fizmatlit, 1961, pp. 715–716.

    Google Scholar 

  16. Davydov, V.A., Rakhmanina, A.V., Agafonov, V.N., Narymbetov, B., Boudou, J.-P., and Szwarc, H., Conversion of polycyclic aromatic hydrocarbons to graphite and diamond at high pressure, Carbon, 2004, vol. 42, no. 2, pp. 261–269.

    Article  CAS  Google Scholar 

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Correspondence to T. D. Varfolomeeva.

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Original Russian Text © T.D. Varfolomeeva, A.G. Lyapin, S.V. Popova, N.F. Borovikov, I.P. Zibrov, V.V. Brazhkin, 2016, published in Neorganicheskie Materialy, 2016, Vol. 52, No. 4, pp. 396–401.

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Varfolomeeva, T.D., Lyapin, A.G., Popova, S.V. et al. Behavior of detonation nanodiamond at high pressures and temperatures in the presence of a hydrogen-containing fluid. Inorg Mater 52, 351–356 (2016). https://doi.org/10.1134/S0020168516040142

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  • DOI: https://doi.org/10.1134/S0020168516040142

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