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Crystallization kinetics of (TeO2)1–x (MoO3) x glasses studied by differential scanning calorimetry

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Abstract

A technique has been proposed for assessing kinetic characteristics (parameters) of glass crystallization from mathematical data processing results for glass crystallization peaks, with allowance for nonisothermal conditions of differential scanning calorimetry. The technique has been used to analyze the crystallization behavior of (TeO2)1–x (MoO3) x (x = 0.25–0.55) glasses, which has made it possible to evaluate crystallization parameters and derive their regression dependences on glass composition. Basic to glassy materials research is that the proposed approach includes a parametrically defined, explicit functional dependence of the degree of crystallization on time and temperature, α(t, T), as a basis for optimizing glass heat treatment conditions in terms of this characteristic and predicting such conditions from regression relationships for previously unexplored compositions in the tellurite–molybdate glass system studied.

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References

  1. Sibirkin, A.A., Zamyatin, O.A., Torokhova, E.V., Churbanov, M.F., Suchkov, A.I., and Moiseev, A.N., Coprecipitation of tellurium and molybdenum oxides from aqueous solutions, Inorg. Mater., 2011, vol. 47, no. 10, pp. 1214–1217.

    Article  CAS  Google Scholar 

  2. Churbanov, M.F., Sibirkin, A.A., and Zamyatin, O.A., RF Patent 2484026, Byull. Izobret, 2013, no. 16.

  3. Sibirkin, A.A., Zamyatin, O.A., Torokhova, E.V., and Suchkov, A.I., Coprecipitation of tellurium(IV) and molybdenum(VI) hydroxides from aqueous hydrochloric acid solutions, Vestn. Nizhegorodsk. Univ. im. N.I. Lobachevskogo, 2008, no. 6, pp. 88–93.

    Google Scholar 

  4. Stkuja, T., Moshida, N., and Ogawa, S., Structural study of MO3–TeO2 glasses, J. Non-Cryst. Solids, 1995, vol. 185, pp. 135–144.

    Article  Google Scholar 

  5. Hohne, G.W.H., Hemminger, W.F., and Flammersheim, H.J., Differential Scanning Calorimetry, Berlin: Springer, 2003, 2nd ed.

    Book  Google Scholar 

  6. Šesták, J., Thermophysical Properties of Solids: Their Measurements and Theoretical Thermal Analysis, Prague: Academia, 1984.

    Google Scholar 

  7. Malek, J., Zmrhalova, Z., Bartak, J., and Honcova, P., A novel method to study crystallization of glasses, Thermochim. Acta, 2010, vol. 511, pp. 67–73.

    Article  CAS  Google Scholar 

  8. Malek, J. and Klikorka, J., Crystallization kinetics of glassy GeS2, J. Therm. Anal., 1987, vol. 32, pp. 1883–1893.

    Article  CAS  Google Scholar 

  9. Prigogine, I. and Kondepudi, D., Modern Thermodynamics: From Heat Engines to Dissipative Structures, Chichester: Wiley, 1998. Translated under the title Sovremennaya termodinamika. Ot teplovykh dvigatelei do dissipativnykh struktur, Moscow: Mir, 2002, p. 461.

    Google Scholar 

  10. Borchard, H.J. and Daniels, F., The application of differential thermal analysis to the study of reaction kinetics, J. Am. Chem. Soc., 1957, vol. 79, pp. 41–46.

    Article  Google Scholar 

  11. Young, D.A., Decomposition of Solids, Oxford: Pergamon, 1966. Translated under the title Kinetika razlozheniya tverdykh veshchestv, Moscow: Mir, 1969, p. 263.

    Google Scholar 

  12. Sestaik, J. and Berggren, G., The study of the kinetics of mechanism of solid-state reactions at increasing temperature, Thermochim. Acta, 1971, vol. 3, pp. 1–12.

    Article  Google Scholar 

  13. Sibirkin, A.A., Zamyatin, O.A., Churbanov, M.F., Moiseev, A.N., and Pimenov, V.G., Impurity composition of molybdate–tellurite glasses prepared from mixtures precipitated from hydrochloric acid solutions of tellurium and molybdenum compounds by ammonia, Inorg. Mater., 2013, vol. 49, no. 2, pp. 219–222.

    Article  CAS  Google Scholar 

  14. Petrini, G. and Bart, J.C.J., Das Phasendiagramm des Systems TeO2–MoO3, Z. Anorg. Allg. Chem., 1981, vol. 474, pp. 229–232.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Lobachevsky State University, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia

    A. M. Kut’in & A. A. Sibirkin

  2. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    A. M. Kut’in & A. D. Plekhovich

Authors
  1. A. M. Kut’in
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  2. A. D. Plekhovich
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  3. A. A. Sibirkin
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Correspondence to A. D. Plekhovich.

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Original Russian Text © A.M. Kut’in, A.D. Plekhovich, A.A. Sibirkin, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 12, pp. 1385–1392.

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Kut’in, A.M., Plekhovich, A.D. & Sibirkin, A.A. Crystallization kinetics of (TeO2)1–x (MoO3) x glasses studied by differential scanning calorimetry. Inorg Mater 51, 1288–1295 (2015). https://doi.org/10.1134/S0020168515120055

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  • DOI: https://doi.org/10.1134/S0020168515120055

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