Abstract
We have studied the effect of mechanical processing of γ-Fe2O3 with the use of a planetary ball mill on the characteristics of resulting powders: phase composition, crystallite size, particle size, and specific surface area. The results demonstrate that the mechanical processing of γ-Fe2O3 leads to the γ-Fe2O3 → α-Fe2O3 phase transition. The formation of α-Fe2O3 is shown to be accompanied by considerable changes in the specific surface area and particle size of the powder material.
Similar content being viewed by others
References
Gubin, S.P., Koksharov, Yu.A., Khomutov, G.B., and Yurkov, G.Yu., Magnetic nanoparticles: preparation, structure, and properties, Usp. Khim., 2005, vol. 74, no. 6, pp. 539–574.
Wei, Z., Wei, X., Wang, S., and He, D., Preparation and visible-light photocatalytic activity of α-Fe2O3/γ-Fe2O3 magnetic heterophase photocatalyst, Mater. Lett., 2014, vol. 118, pp. 107–110.
Kishimoto, M., Minagawa, M., Yanagihara, H., Oda, T., Ohkochi, N., and Kita, E., Synthesis and magnetic properties of platelet γ-Fe2O3 particles for medical applications using hysteresis-loss heating, J. Magn. Magn. Mater., 2012, vol. 324, pp. 1285–1289.
Li, P., Deng, J., Li, Y., Liang, W., Wang, K., Kang, L., Zeng, S., Yin, S., Zhao, Z., Liu, X., Yang, Y., and Gao, F., One-step solution combustion synthesis of Fe2O3/C nano-composites as anode materials for lithium ion batteries, J. Alloys Compd., 2014, vol. 590, pp. 318–323.
Boldyrev, V.V., Mechanochemistry and mechanical activation, Usp. Khim., 2006, vol. 75, no. 3, pp. 203–216.
Arbain, R., Othman, M., and Palaniandy, S., Preparation of iron oxide nanoparticles by mechanical milling, Miner. Eng., 2011, vol. 24, pp. 1–9.
Leminea, O.M., Sajieddine, M., Bououdina, M., Msalam, R., Mufti, S., and Alyamani, A., Rietveld analysis and Mössbauer spectroscopy studies of nanocrystalline hematite α-Fe2O3, J. Alloys Compd., 2010, vol. 502, pp. 279–282.
Hofmann, M., Campbell, S.J., Kaczmarek, W.A., and Welzel, S., Mechanochemical transformation of α-Fe2O3 to Fe3 − x O4—microstructural investigation, J. Alloys Compd., 2003, vol. 348, pp. 278–284.
Liu, X.H., Cui, W.B., Liu, W., Zhao, X.G., Li, D., and Zhang, Z.D., Exchange bias and phase transformation in α-Fe2O3/Fe3O4 nanocomposites, J. Alloys Compd., 2009, vol. 475, pp. 42–45.
Dutta, S., Manik, S.K., Pal, M., Pradhan, S.K., Brahma, P., and Chakravorty, D., Electrical conductivity in nanostructured magnetite-hematite composites produced by mechanical milling, J. Magn. Magn. Mater., 2005, vol. 288, pp. 301–306.
Hajra, P., Basu, S., Dutta, S., Brahma, P., and Chakravorty, D., Exchange bias in ferrimagnetic-antiferromagnetic nanocomposite produced by mechanical attrition, J. Magn. Magn. Mater., 2009, vol. 321, pp. 2269–2275.
Hsiang, H.-I. and Yen, F.-S., Effects of mechanical treatment on phase transformation and sintering of nano-sized γ-Fe2O3 powder, Ceram. Int., 2003, vol. 29, pp. 1–6.
Morales, J., Tirado, J.L., and Valera, C., Preferential X-ray line broadening and thermal behavior of γ-Fe2O3, J. Am. Ceram. Soc., 1989, vol. 72, pp. 1244–1246.
Lukashev, R.V., Klyamkin, S.N., and Tarasov, B.P., Preparation and properties of hydrogen-storage composites in the MgH2-C system, Inorg. Mater., 2006, vol. 42, no. 7, pp. 726–732.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © R.V. Lukashev, A.F. Alekova, S.K. Korchagina, F.Kh. Chibirova, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 2, pp. 176–179.
Rights and permissions
About this article
Cite this article
Lukashev, R.V., Alekova, A.F., Korchagina, S.K. et al. Mechanical processing of γ-Fe2O3 . Inorg Mater 51, 134–137 (2015). https://doi.org/10.1134/S0020168515010100
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168515010100