Abstract
We have studied the formation of BaTi1 − x Zr x O3 solid solutions with the perovskite structure. The phase composition, microstructure, and electrical properties of the BaTi1 − x Zr x O3 materials have been investigated. The results demonstrate that their dielectric permittivity (ɛ) and loss tangent (tan δ) decrease with increasing zirconium content. At the same time, their nonlinearity coefficient (n R) remains large (n R = 30–50%) in relatively low fields (E = 30–50 kV/cm). The present data suggest that the materials studied here are potentially attractive for use in creating nonlinear devices of modern microelectronics.
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Vendik, O.G., Segnetoelektriki v tekhnike SVCh (Ferroelectrics in Microwave Engineering), Vendik, O.G., Ed., Moscow: Sovetskoe Radio, 1979.
Kozyrev, A., Ivanov, A., Samoilova, T., Soldatenkov, O., Astafiev, K., and Sengupta, L.C., Nonlinear response and power handling capability of ferroelectric BaxSr1 − x TiO3 film capacitors and tunable microwave devices, J. Appl. Phys., 2000, vol. 88, pp. 5334–5342.
Tagantsev, A.K., Sherman, V.O., Astafiev, K.F., Venkatesh, J., and Setter, N., Ferroelectric materials for microwave tunable applications, J. Electroceram., 2003, vol. 11, pp. 5–66.
Mitoseriu, L., Ciomaga, C.E., Buscaglia, V., et al., Hysteresis and tunability characteristics of Ba(Zr,Ti)O3 ceramics described by first order reversal curves diagrams, J. Eur. Ceram. Soc., 2007, vol. 27, pp. 3723–3726.
Nuzhnyy, D., Petzelt, J., and Savinov, M., Broadband dielectric response of Ba(Zr,Ti)O3 ceramics: from incipient via relaxor and diffuse up to classical ferroelectric behavior, Phys. Rev. B: Condens. Matter Mater. Phys., 2012, vol. 86, paper 014 106.
Rui-hong Liang, Xian-lin Dong, Ying Chen, Fei Cao, and Yong-ling Wang, Dielectric properties and tunability of Ba(ZrxTi1 − x )O3 ceramics under high dc electric field, Ceram. Int., 2007, vol. 33, pp. 957–961.
Ubaldini, A., Buscaglia, V., Uliana, C., Costa, G., and Ferretti, M., Kinetics and mechanism of formation of barium zirconate from barium carbonate and zirconia powders, J. Am. Ceram. Soc., 2003, vol. 86, pp. 19–25.
Bera, J. and Rout, S.K., On the formation mechanism of BaTiO3-BaZrO3 solid solution through solid-oxide reaction, Mater. Lett., 2005, vol. 59, pp. 135–138.
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Original Russian Text © A.N. Suslov, D.A. Durilin, O.V. Ovchar, A.G. Belous, Bostjan Jancar, Matjaz Spreitzer, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 11, pp. 1216–1221.
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Suslov, A.N., Durilin, D.A., Ovchar, O.V. et al. Synthesis and dielectric and nonlinear properties of BaTi1 − x Zr x O3 ceramics. Inorg Mater 50, 1125–1130 (2014). https://doi.org/10.1134/S0020168514110193
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DOI: https://doi.org/10.1134/S0020168514110193