Skip to main content
Log in

Study of the thermodynamic properties of a hydrogen-absorbing alloy LaFe0.1Mn0.3Ni4.8 for systems for hydrogen storage and purification

  • Thermophysical Properties of Materials
  • Published:
High Temperature Aims and scope

Abstract

The article is devoted to methodological problems of investigation of the pressure-concentration-temperature (PCT) phase diagrams of hydrogen-absorbing materials that are used in metal hydride systems for storage and purification of hydrogen based on intermetallic compounds of the AB5-type. The problem is discussed with an example of the PCT-diagram of the LaFe0.1Mn0.3Ni4.8 alloy, which is promising for creation of metal hydride systems for storage and purification of hydrogen integrated with power plants (with a power of up to 5 kW) based on fuel cells with a solid-polymer electrolyte.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Energeticheskaya strategiya Rossiiskoi Federatsii do 2030 g. (Energy Strategy of the Russian Federation until 2030), Moscow, 2009.

  2. Shishkin, A.N., in Doklad na vsemirnom elektrotekhnicheskom kongresse VELK-2011 (Report on the XII World Electrotechnical Congress “WELC 2011,” Moscow, Russia, October 4–5, 2011, Moscow, 2011.

    Google Scholar 

  3. Budargin, O.M., Malyshenko, S.P., and Shishkin, A.N., in Innovatsionnye tekhnologii v energetike (Innovative Technologies in Power Engineering: Book 2), Moscow: Nauka, 2012, p. 5.

    Google Scholar 

  4. Malyshenko, S.P., Borzenko, V.I., Dunikov, D.O., and Nazarova, O.V., Therm. Eng., 2012, vol. 59, no. 6, p. 468.

    Article  ADS  Google Scholar 

  5. Tarasov, B.P., Burnasheva, V.V., Lototskii, M.V., and Yartys’, V.A., Altern. Energy Ekol., 2005, no. 12, p. 14.

    Google Scholar 

  6. Borzenko, V.I., Extended Abstract of Cand. Sci. (Eng.) Dissertation, Moscow: Joint Institute for High Temperature of the Russian Academy of Sciences, 2012.

    Google Scholar 

  7. Borzenko, V.I., Dunikov, D.O., and Malyshenko, S.P., High Temp., 2011, vol. 49, no. 2, p. 249.

    Article  Google Scholar 

  8. Kovba, L.M., Rentgenografiya v neorganicheskoi khimii (X-Ray Diffraction in Inorganic Chemistry), Moscow: Moscow State University, 1991.

    Google Scholar 

  9. Mueller, W.M., Blackledge, J.P., and Libowitz, G.G., Metal Hydrides, London: Academic, 1968.

    Google Scholar 

  10. Hemmes, H., Driessen, A., and Griessen, R., J. Phys. C: Solid State Phys., 1986, vol. 19, p. 3571.

    Article  ADS  Google Scholar 

  11. Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (A Reference Book on Thermal and Physical Properties of Gases and Liquids), Moscow: Nauka, 1972.

    Google Scholar 

  12. McCarty, R.D., Hydrogen Technological Survey Thermophysical Properties, Washington, D.C.: NASA, 1975, p. 272.

    Google Scholar 

  13. Kiersted, H., J. Less-Common Met., 1980, vol. 71, p. 303.

    Article  Google Scholar 

  14. Broom, D.P., Int. J. Hydrogen Energy, 2007, vol. 32, p. 4871.

    Article  Google Scholar 

  15. Buckley, C.E., Gray, E.M.A., and Kisi, E.H., J. Alloys Compd., 1994, vol. 215, p. 195.

    Article  Google Scholar 

  16. Gray, E.M.A., Buckley, C.E., and Kisi, E.H., J. Alloys Compd., 1994, vol. 215, nos. 1–2, p. 201.

    Article  Google Scholar 

  17. Gray, E.M.A. and Kisi, E.H., J. Alloys Compd., 1995, vol. 217, p. 112.

    Article  Google Scholar 

  18. Buckley, C.E., Gray, E.M.A., and Kisi, E.H., J. Alloys Compd., 1995, vol. 231, p. 460.

    Article  Google Scholar 

  19. Gray, E.M.A., Blach, T.P., and Buckley, C.E., J. Alloys Compd., 1999, vol. 293–295, p. 57.

    Article  Google Scholar 

  20. Rouquerol, F., Rouquerol, J., and Sing, K., Adsorption by Powders and Porous Solids: Principles, Methodology, and Applications, London: Academic Press, 1999.

    Google Scholar 

  21. Japanese Industrial Standards Committee: Method of Determining the PCT Relations of Hydrogen-Absorbing Alloys, JIS H 7201, 1991.

  22. Blackman, J.M., Patrick, J.W., and Snape, C.E., Carbon, 2006, vol. 44, p. 918.

    Article  Google Scholar 

  23. Gerard, N., Belkbir, L., and Joly, E., J. Phys. E: Sci. Instrum., 1979, vol. 12, p. 476.

    Article  ADS  Google Scholar 

  24. Wang, X-L. and Suda, S., J. Alloys Compd., 1995, vol. 231, nos. 1–2, p. 660.

    Article  Google Scholar 

  25. Flanagan, T.B. and Oates, W.A., J. Alloys Compd., 2005, vols. 404–406, p. 16.

    Article  Google Scholar 

  26. Topics in Applied Physics: Hydrogen in Metals II. Application-Oriented Properties, Völkl, A.G., Ed., Berlin: Springer-Verlag, 1978.

    Google Scholar 

  27. Verbetsky, V.N., Malyshenko, S.P., Mitrochin, S.V., Solovey, V.V., and Smal’ko, Yu.F., Int. J. Hydrogen Energy, 1998, vol. 23, no. 12, p. 1165.

    Article  Google Scholar 

  28. Abramov, Yu.A., Krivtsova, V.I., and Solovei, V.V., Sistemy khraneniya i podachi vodoroda na osnove tverdykh veshchestv dlya bortovykh energeticheskikh ustanovok (Systems of Storage and Supply of Hydrogen Based on the Solids for Onboard Power Plants), Kharkiv: Folio, 2002.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. P. Malyshenko.

Additional information

Original Russian Text © S.P. Malyshenko, I.A. Romanov, 2014, published in Teplofizika Vysokikh Temperatur, 2014, Vol. 52, No. 3, pp. 415–422.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Malyshenko, S.P., Romanov, I.A. Study of the thermodynamic properties of a hydrogen-absorbing alloy LaFe0.1Mn0.3Ni4.8 for systems for hydrogen storage and purification. High Temp 52, 403–410 (2014). https://doi.org/10.1134/S0018151X14020163

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018151X14020163

Keywords

Navigation