Abstract
The article is devoted to methodological problems of investigation of the pressure-concentration-temperature (PCT) phase diagrams of hydrogen-absorbing materials that are used in metal hydride systems for storage and purification of hydrogen based on intermetallic compounds of the AB5-type. The problem is discussed with an example of the PCT-diagram of the LaFe0.1Mn0.3Ni4.8 alloy, which is promising for creation of metal hydride systems for storage and purification of hydrogen integrated with power plants (with a power of up to 5 kW) based on fuel cells with a solid-polymer electrolyte.
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References
Energeticheskaya strategiya Rossiiskoi Federatsii do 2030 g. (Energy Strategy of the Russian Federation until 2030), Moscow, 2009.
Shishkin, A.N., in Doklad na vsemirnom elektrotekhnicheskom kongresse VELK-2011 (Report on the XII World Electrotechnical Congress “WELC 2011,” Moscow, Russia, October 4–5, 2011, Moscow, 2011.
Budargin, O.M., Malyshenko, S.P., and Shishkin, A.N., in Innovatsionnye tekhnologii v energetike (Innovative Technologies in Power Engineering: Book 2), Moscow: Nauka, 2012, p. 5.
Malyshenko, S.P., Borzenko, V.I., Dunikov, D.O., and Nazarova, O.V., Therm. Eng., 2012, vol. 59, no. 6, p. 468.
Tarasov, B.P., Burnasheva, V.V., Lototskii, M.V., and Yartys’, V.A., Altern. Energy Ekol., 2005, no. 12, p. 14.
Borzenko, V.I., Extended Abstract of Cand. Sci. (Eng.) Dissertation, Moscow: Joint Institute for High Temperature of the Russian Academy of Sciences, 2012.
Borzenko, V.I., Dunikov, D.O., and Malyshenko, S.P., High Temp., 2011, vol. 49, no. 2, p. 249.
Kovba, L.M., Rentgenografiya v neorganicheskoi khimii (X-Ray Diffraction in Inorganic Chemistry), Moscow: Moscow State University, 1991.
Mueller, W.M., Blackledge, J.P., and Libowitz, G.G., Metal Hydrides, London: Academic, 1968.
Hemmes, H., Driessen, A., and Griessen, R., J. Phys. C: Solid State Phys., 1986, vol. 19, p. 3571.
Vargaftik, N.B., Spravochnik po teplofizicheskim svoistvam gazov i zhidkostei (A Reference Book on Thermal and Physical Properties of Gases and Liquids), Moscow: Nauka, 1972.
McCarty, R.D., Hydrogen Technological Survey Thermophysical Properties, Washington, D.C.: NASA, 1975, p. 272.
Kiersted, H., J. Less-Common Met., 1980, vol. 71, p. 303.
Broom, D.P., Int. J. Hydrogen Energy, 2007, vol. 32, p. 4871.
Buckley, C.E., Gray, E.M.A., and Kisi, E.H., J. Alloys Compd., 1994, vol. 215, p. 195.
Gray, E.M.A., Buckley, C.E., and Kisi, E.H., J. Alloys Compd., 1994, vol. 215, nos. 1–2, p. 201.
Gray, E.M.A. and Kisi, E.H., J. Alloys Compd., 1995, vol. 217, p. 112.
Buckley, C.E., Gray, E.M.A., and Kisi, E.H., J. Alloys Compd., 1995, vol. 231, p. 460.
Gray, E.M.A., Blach, T.P., and Buckley, C.E., J. Alloys Compd., 1999, vol. 293–295, p. 57.
Rouquerol, F., Rouquerol, J., and Sing, K., Adsorption by Powders and Porous Solids: Principles, Methodology, and Applications, London: Academic Press, 1999.
Japanese Industrial Standards Committee: Method of Determining the PCT Relations of Hydrogen-Absorbing Alloys, JIS H 7201, 1991.
Blackman, J.M., Patrick, J.W., and Snape, C.E., Carbon, 2006, vol. 44, p. 918.
Gerard, N., Belkbir, L., and Joly, E., J. Phys. E: Sci. Instrum., 1979, vol. 12, p. 476.
Wang, X-L. and Suda, S., J. Alloys Compd., 1995, vol. 231, nos. 1–2, p. 660.
Flanagan, T.B. and Oates, W.A., J. Alloys Compd., 2005, vols. 404–406, p. 16.
Topics in Applied Physics: Hydrogen in Metals II. Application-Oriented Properties, Völkl, A.G., Ed., Berlin: Springer-Verlag, 1978.
Verbetsky, V.N., Malyshenko, S.P., Mitrochin, S.V., Solovey, V.V., and Smal’ko, Yu.F., Int. J. Hydrogen Energy, 1998, vol. 23, no. 12, p. 1165.
Abramov, Yu.A., Krivtsova, V.I., and Solovei, V.V., Sistemy khraneniya i podachi vodoroda na osnove tverdykh veshchestv dlya bortovykh energeticheskikh ustanovok (Systems of Storage and Supply of Hydrogen Based on the Solids for Onboard Power Plants), Kharkiv: Folio, 2002.
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Original Russian Text © S.P. Malyshenko, I.A. Romanov, 2014, published in Teplofizika Vysokikh Temperatur, 2014, Vol. 52, No. 3, pp. 415–422.
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Malyshenko, S.P., Romanov, I.A. Study of the thermodynamic properties of a hydrogen-absorbing alloy LaFe0.1Mn0.3Ni4.8 for systems for hydrogen storage and purification. High Temp 52, 403–410 (2014). https://doi.org/10.1134/S0018151X14020163
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DOI: https://doi.org/10.1134/S0018151X14020163