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Nitride Coatings Based on a High-Entropy Alloy Formed by the Ion-Plasma Method

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Abstract

Nitride coatings based on the high-entropy alloy with the elemental composition of TiNbZrTaHf were formed by deposition onto a solid substrate in vacuum from a multi-component gas-metal plasma created by vacuum arc cathode evaporation with plasma assistance in a mixture of nitrogen and argon. It was shown that the coatings are a single-phase (FCC crystal structure; a = 0.4508 nm) nanocrystalline (2.5–3 nm) material with a hardness of 26 GPa and a Young’s modulus of 359.2 GPa.

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REFERENCES

  1. Cantor, B., Chang, I.T.H., Knight, P., and Vincent, A.J.B., Mater. Sci. Eng., A, 2004, vols. 375–377, p. 213.

    Article  Google Scholar 

  2. Yeh, J.W., Adv. Eng. Mater., 2004, vol. 6, p. 299.

    Article  CAS  Google Scholar 

  3. Chen, T.K., Shun, T.T., Yeh, J.W., and Wong, M.S., Surf. Coat. Technol., 2004, vols. 188–189, p. 193.

    Article  Google Scholar 

  4. Chen, T.K., Wong, M.S., Shun, T.T., and Yeh, J.W., Surf. Coat. Technol., 2005, vol. 200, p. 1361.

    Article  CAS  Google Scholar 

  5. Rong, Z., Wang, C., Wang, Y., et al., J. Alloys Compd., 2022, vol. 921, p. 166061.

    Article  CAS  Google Scholar 

  6. Ma, Y., Peng, G.J., Ven, D.H., and Zhang, T.H., Mater. Sci. Eng., A, 2015, vol. 621, p. 111.

    Article  CAS  Google Scholar 

  7. Tsai, D.-C., Shieu, F.-S., Chang, S.-Y., et al., J. Electrochem. Soc., 2010, vol. 157, no. 3, p. K52.

    Article  CAS  Google Scholar 

  8. Huang, P.-K. and Yeh, J.-W., Scr. Mater., 2010, vol. 62, p. 105.

    Article  CAS  Google Scholar 

  9. Wang, L.M., Chen, G.G., Yeh, J.W., and Ke, S.T., Mater. Chem. Phys., 2011, vol. 126, p. 880.

    Article  CAS  Google Scholar 

  10. Meghwal, A., Anupam, A., Murty, B.S., et al., J. Therm. Spray Technol., 2020, vol. 29, p. 857.

    Article  CAS  Google Scholar 

  11. Hui, Z., Wu, W., He, Y., Li, M.X., and Guo, S., Appl. Surf. Sci., 2015, vol. 36, p. 543.

    Google Scholar 

  12. Gao, W.Y., Chang, C., Li, G., et al., Optik, 2019, vol. 178, p. 950.

    Article  CAS  Google Scholar 

  13. Gorban, V.F., Andreev, A.A., Shaginyan, L.R., et al., J. Superhard Mater., 2018, vol. 40, no. 2, p. 88.

    Article  Google Scholar 

  14. Ivanov, Y.F., Akhmadeev, Y.Kh., Koval, N.N., et al., Izv. Vyssh. Uchebn. Zaved., Fiz., 2022, vol. 65, no. 11, p. 59.

    CAS  Google Scholar 

  15. Ivanov, Yu.F., Koval, N.N., Krysina, O.V., et al., Surf. Coat. Technol., 2012, vol. 207, p. 430.

    Article  CAS  Google Scholar 

  16. Krysina, O.V., Koval, N.N., Shmakov, A.N., et al., J. Phys.: Conf. Ser., 2016, vol. 669, p. 12034.

    Google Scholar 

  17. Timchenko, N.A., Zubavichus, Y.V., Krysina, O.V., et al., J. Surf. Invest.: X-ray, Synchrotron Neutron Tech., 2016, vol. 10, no. 2. p. 425.

    Article  CAS  Google Scholar 

  18. Schroeder J.L., Thomson W., Howard B. et al., Rev. Sci. Instrum., 2015, vol. 86, p. 95113.

    Article  CAS  Google Scholar 

  19. Aschauer, E., Bartosik, M., Bolvardi, H., et al., Surf. Coat. Technol., 2019, vol. 361, p. 364.

    Article  CAS  Google Scholar 

  20. Fyrstov, S.A., Gorban, V.F., Andreev, A.O., and Krapivka, N.A., Sci. Innov., 2013, vol. 9, no. 5, p. 32.

    Google Scholar 

  21. Gorban, V.F., Andreev, A.A., Shaginyan, L.R., et al., J. Superhard Mater., 2018, vol. 40, no. 2, p. 88.

    Article  Google Scholar 

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Funding

This work was carried out with the financial support of the Russian Federation through the Ministry of Science and Higher Education (project no. 075-15-2021-1348) within the framework of events nos. 3.1.4, 3.1.5, 3.1.12, and 3.1.13.

The research was carried out using the equipment of the CSU NMNT TPU, supported by the RF MES project no. 075-15-2021-710.

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Correspondence to Yu. F. Ivanov.

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Ivanov, Y.F., Akhmadeev, Y.H., Koval, N.N. et al. Nitride Coatings Based on a High-Entropy Alloy Formed by the Ion-Plasma Method. High Energy Chem 57 (Suppl 1), S77–S80 (2023). https://doi.org/10.1134/S0018143923070172

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  • DOI: https://doi.org/10.1134/S0018143923070172

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