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The Role of Ozone in Chemical Processes in Electric Discharge Plasma

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Abstract

The mechanism of formation of an ozone–hydroxyl mixture and its properties have been investigated. The main channel for the consumption of hydroxyl radicals is the buildup of hydrogen peroxide. In the absence of ozone, almost all OH• radicals formed are converted to hydrogen peroxide. In the presence of ozone, the reaction O3 + H2O2 gives hydroxyl radicals again. The concentration of OH• radicals is maintained until ozone and hydrogen peroxide are consumed. This allows the transport of hydroxyl radicals up to 45 cm from the reactor. The results are confirmed by an experiment on the oxidation of oxalic acid.

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REFERENCES

  1. Bruggeman, P.J., Kushner, M.J., Locke, B.R., et al., Plasma Sources Sci. Technol., 2016, vol. 25, no. 59, p. 053002.

    Google Scholar 

  2. Handbook of Chemistry and Physics, 97th ed., Haynes, W.M., Ed., Boca Raton: CRC, 2016–2017, p. 97.

  3. Li, L., Nikiforov, A., Xiong, Q., Britun, N., Snyders, R., et al., Phys. Plasmas, 2013, vol. 20, p. 093502.

    Google Scholar 

  4. Aristova, N.A. and Piskarev, I.M., Russ. J. Phys. Chem., 2003, vol. 77, no. 5, p. 723.

    Google Scholar 

  5. Raizer, Yu.P., Gas Discharge Physics, Berlin: Springer, 1991.

    Google Scholar 

  6. Charlot, G., Les méthodes de la chimie analytique: analyse quantitative minérale, 5th Ed., Paris: Masson et Cie, 1966.

    Google Scholar 

  7. Piskarev, I.M., Russ. J. Phys. Chem., 2001, vol. 75, no. 11, p. 1832.

    Google Scholar 

  8. Pastina, B. and LaVerne, J.A., J. Phys. Chem. A, 2001, p. 9316.

  9. Westley, F., Tables of Recommended Rate Constants for Chemical Reactions Occurring in Combustion, Washington, DC: National Bureau of Standards, 1980.

    Google Scholar 

  10. Hoigne, J., Bader, H., Haag, W.R., and Staehelin, J., Water Res., 1985, vol. 19, no. 8, p. 993.

    Google Scholar 

  11. Kulagin, Y.A., Shelepin, L.A., and Yarygina, V.N., Kinetics of Processes in the Gas Media Containing Metastable Oxygen, Moscow: Lebedev FIAN, 1994.

    Google Scholar 

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Authors and Affiliations

  1. Skobeltsyn Research Institute of Nuclear Physics, Moscow State University, 119234, Moscow, Russia

    I. M. Piskarev

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  1. I. M. Piskarev
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Correspondence to I. M. Piskarev.

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Translated by S. Zatonsky

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Piskarev, I.M. The Role of Ozone in Chemical Processes in Electric Discharge Plasma. High Energy Chem 54, 205–209 (2020). https://doi.org/10.1134/S001814392003011X

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  • DOI: https://doi.org/10.1134/S001814392003011X

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