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Reverse Photochromism of Nitrosubstituted Bisspiropyran Based on Benzopyrroloindole

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Abstract

The photochromic properties of new di- and tetranitrobisspiropyrans have been studied. Dinitrobisspiropyran solutions are characterized by direct photochromism, whereas reverse photochromism—coloration of the solution in the dark and its discoloration under the action of visible or UV light—is observed in solutions of tetranitrobisspiropyran in polar and weakly polar solvents and in polymer matrices of poly(methyl methacrylate) (PMMA) and polyvinyl butyral (PVB). The features of reverse photochromism are discussed, and a comparison with the photochromism of model nitrosubstituted monospiropyrans and dinitrobisspiropyran is carried out.

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ACKNOWLEDGMENTS

This work was carried out under the program of the State Assignment 0082-2018-0006 and 0082-2014-0015 and supported by the Russian Foundation for Basic Research, project no. 16-03-00275.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    I. R. Mardaleishvili, G. V. Lyubimova, A. V. Lyubimov, L. S. Kol’tsova, A. I. Shienok, P. P. Levin & N. L. Zaichenko

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334, Moscow, Russia

    P. P. Levin & A. S. Tatikolov

Authors
  1. I. R. Mardaleishvili
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  2. G. V. Lyubimova
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  3. A. V. Lyubimov
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  4. L. S. Kol’tsova
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  5. A. I. Shienok
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  6. P. P. Levin
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  7. A. S. Tatikolov
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  8. N. L. Zaichenko
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Correspondence to I. R. Mardaleishvili.

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Translated by A. Tatikolov

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Mardaleishvili, I.R., Lyubimova, G.V., Lyubimov, A.V. et al. Reverse Photochromism of Nitrosubstituted Bisspiropyran Based on Benzopyrroloindole. High Energy Chem 53, 13–21 (2019). https://doi.org/10.1134/S0018143919010089

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  • DOI: https://doi.org/10.1134/S0018143919010089

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