Skip to main content
SpringerLink
Log in

Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile

  • Photonics
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone (CH1) and its bis(aza-18-crown-6) derivative (CH2) in acetonitrile at ambient temperature and 77 K have been studied. The absorption, fluorescence, and phosphorescence spectra of CH1 and CH2 are similar. The probability of the formation of the triplet state is higher for CH2 molecules (λT-T max = 660 nm, lifetime τT ~ 20 μs). The lifetime of the CH1 molecule in the triplet state is estimated at τT ~ 2–3 μs. Photoisomers of CH1 and CH2 are formed along with the triplet state. According to DFT calculation results, the formation of trans–cis photoisomers of CH1 and CH2 is the most energetically favorable.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mondal, J.A.L., Verma, S., Ghosh, H.N., and Palit, D.K, J. Chem. Sci., 2008, vol. 120, no. 1, p. 45.

    Article  CAS  Google Scholar 

  2. Sakar, A., Kedia, N., Purkayastha, P., and Dagchi, S., J. Lumin., 2012, vol. 132, p. 2345.

    Article  Google Scholar 

  3. Doroshenko, A.O., Sychevskaya, L.B., Grygorovych, A.V., and Pivovarenko, V.G., J. Fluoresc., 2002, vol. 12, no. 3/4, p. 455.

    Article  CAS  Google Scholar 

  4. Rurack, K., Dekhtyar, M.L., Bricks, J.L., Resch-Genger, U., and Rettig, W., J. Phys. Chem. A, 1999, vol. 103, no. 48, p. 9626.

    Article  CAS  Google Scholar 

  5. Chambers, W.J. and Eaton, D.F., J. Imag. Sci., 1986, vol. 30, no. 5, p. 230.

    CAS  Google Scholar 

  6. Marcotte, N., Fery-Forgues, S., Lavabre, D., Marguet, S., and Pivovarenko, V.G., J. Phys. Chem. A, 1999, vol. 103, no. 17, p. 3163.

    Article  CAS  Google Scholar 

  7. Doroshenko, A.O., Grigorovich, A.V., Posokhov, E.A., Pivovarenko, V.G., and Demchenko, A.P., Mol. Eng., 1998, vol. 8, no. 3, p. 199.

    Article  CAS  Google Scholar 

  8. Basu, J.K., Shannigrahi, M., and Bagchi, S., J. Phys. Chem. A, 2007, vol. 111, no. 30, p. 7066.

    Article  CAS  Google Scholar 

  9. Zakharova, G.V., Zyuz’kevich, F.S., Nuriev, V.N., Vatsadze, S.Z., Plotnikov, V.G., Gromov, S.P., and Chibisov, A.K., High Energy Chem., 2016, vol. 50, no. 1, p. 29.

    Article  Google Scholar 

  10. Marcotte, N. and Fery-Forgues, S., J. Photochem. Photobiol., A, 2000, vol. 130, p. 133.

    Article  CAS  Google Scholar 

  11. Vatsadze, S.Z., Manaenkova, M.A., Sviridenkova, N.V., Zyk, N.V., Krut’ko, D.P., Churakov, A.V., Antipin, M.Yu., and Howard, D.A.L., and Lang. G, Izv. Akad. Nauk, Ser. Khim., 2006, vol. 55, no. 7, p. 1141.

    Google Scholar 

  12. Atabekyan, L.S. and Chibisov, A.K., High Energy Chem., 2007, vol. 41, no. 2, p. 91.

    Article  CAS  Google Scholar 

  13. Zakharova, G.V., Avakyan, V.G., Markelov, V.P., Svyatoslavskii, N.L., Svyatoslavskaya, T.A., and Chibisov, A.K., High Energy Chem., 2015, vol. 49, no. 6, p. 407.

    Article  CAS  Google Scholar 

  14. Laikov, D.N., Chem Phys. Lett., 1997, vol. 28, p. 151.

    Article  Google Scholar 

  15. Laikov, D.N. and Ustynyuk, Yu.A., Izv. Akad. Nauk, Ser. Khim., 2005, vol. 54, no. 3, p. 804.

    Google Scholar 

  16. Dyadyusha, G.G., Rykov, A.A., and Slominskii, Yu.L., Teor. Eksp. Khim., 1977, vol. 13, no. 4, p. 539.

    CAS  Google Scholar 

  17. Plotnikov, V.G., Int. J. Quantum Chem., 1979, vol. 36, no. 3, p. 527.

    Article  Google Scholar 

  18. Plotnikov, V.G., Usp. Khim., 1980, vol. 49, no. 2, p. 327.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Photochemistry Center, Russian Academy of Sciences, ul. Novatorov 7a, bldg. 1, Moscow, 119421, Russia

    G. V. Zakharova, F. S. Zyuz’kevich, V. N. Gutrov, V. G. Plotnikov, V. G. Avakyan, S. P. Gromov & A. K. Chibisov

  2. Moscow State University, Moscow, 119232, Russia

    V. N. Nuriev, S. Z. Vatsadze & S. P. Gromov

  3. Tomsk State University, pr. Lenina 36, Tomsk, 634050, Russia

    V. G. Plotnikov

Authors
  1. G. V. Zakharova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. S. Zyuz’kevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. N. Gutrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Nuriev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Z. Vatsadze
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. G. Plotnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. G. Avakyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. S. P. Gromov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. A. K. Chibisov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. V. Zakharova.

Additional information

Original Russian Text © G.V. Zakharova, F.S. Zyuz’kevich, V.N. Gutrov, V.N. Nuriev, S.Z. Vatsadze, V.G. Plotnikov, V.G. Avakyan, S.P. Gromov, A.K. Chibisov, 2016, published in Khimiya Vysokikh Energii, 2016, Vol. 50, No. 6, pp. 467–471.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zakharova, G.V., Zyuz’kevich, F.S., Gutrov, V.N. et al. Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile. High Energy Chem 50, 442–446 (2016). https://doi.org/10.1134/S0018143916060205

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143916060205

Keywords

Search

Navigation