Abstract
A CO oxidation catalyst based on β–SiC and Pt nanoparticles has been synthesized and studied. The average size of Pt clusters on the surface of the plasma-chemical silicon carbide nanoparticles is close to 4 nm. It has been found that the rate of the CO oxidation reaction at low concentrations (100 mg/m3) in air at room temperature over the catalyst based on platinum and silicon carbide nanoparticles is 60–90 times that over a platinum black-based catalyst with a specific surface area of 30 m2/g. The Pt/SiC catalyst containing 12 wt % Pt has been found to provide the maximum CO oxidation rate.
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Haruta, M., Kobayashi, T., Sano, H., and Yamada, N., Chem. Lett., 1987, vol. 16, p. 405.
Vershinin, N.N., Gol’dshleger, N.F., Efimov, O.N., and Gusev, A.L., Al’tern. Energ. Ekol., 2008, no. 8, p. 99.
Zhang, L., Li, H., Huang, X., Sun, X., Jiang, Z., Schlogl, R., and Su, D., Angew. Chem., 2015, vol. 127, p. 1.
Lin, S., Ye, X., Johnson, R.S., and Guo, H., J. Phys. Chem. C, 2013, vol. 117, p. 17319.
Rashkeev, N.S., Lupini, A.R., Overbury, S.H., Pennycook, S.J., and Pantelides, S.T., Phys. Rev. B, 2007, vol. 47, p. 1.
Du, V., Sun, D., Yang, H., Huang, J., Jing, X., Odoom-Wubah, T., Wang, H., Jia, L., and Li, Q., J. Phys. Chem. C, 2014, vol. 118, p. 19150.
Vershinin, N.N. and Efimov, O.N., RU Patent no. 2348090 (2009).
Vershinin, N.N., Efimov, O.N., Bakaev, V.A., Aleksenskii, A.E., Baidakova, M.V., Sitnikova, A.A., and Vul, A.Ya., Fullerenes, Nanotubes Carb. Nanostruct., 2011, vol. 19, no. 1, p. 63.
Kabachkov, E.N., Berestenko, V.I., Kurkin, E.N., Torbov, V.I., and Domashnev, I.A., in Ul’tradispersnye poroshki, nanostruktury, materialy (Ultrafine Powders, Nanostructures, and Materials), Krasnoyarsk, 2015, p. 12.
Yang, J., Chen, X., Xianfeng, X., and Ying, J.Y., Energy Environ. Sci., 2012, vol. 5, no. 10, p. 8976.
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Original Russian Text © N.N. Vershinin, V.A. Bakaev, V.I. Berestenko, O.N. Efimov, E.N. Kurkin, E.N. Kabachkov, 2017, published in Khimiya Vysokikh Energii, 2017, Vol. 51, No. 1, pp. 50–54.
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Vershinin, N.N., Bakaev, V.A., Berestenko, V.I. et al. Synthesis and properties of a platinum catalyst supported on plasma chemical silicon carbide. High Energy Chem 51, 46–50 (2017). https://doi.org/10.1134/S0018143916060199
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DOI: https://doi.org/10.1134/S0018143916060199