Abstract
The dynamics of differential absorption spectra of gold nanoparticles has been studied by femtosecond laser spectroscopy over a wide range of excitation energy density. The position of the plasmon resonance peak strongly depends on the dielectric properties of the medium, thereby allowing the use of plasmonic nanoparticles as an optical probe. It has been shown that femtosecond laser spectroscopy techniques, involving analysis of differential absorption spectra of gold nanoparticles in aqueous colloid nanolayer, make it possible to characterize the state of a water nanolayer surrounding the nanoparticle. In particular, at a high excitation energy density, the plasmon resonance absorption band exhibits spectral—kinetic features that suggest vaporization in the nanolayer around the gold particle.
Similar content being viewed by others
References
Le Ru, E.C. and Etchegoin, P.G., Principles of SurfaceEnhanced Raman Spectroscopy and Related Plasmonic Effects, Amsterdam: Elsevier, 2009.
Letfullin, R., Joenathan, C., George, T., and Zahrkov, V., Nanomedicine, 2006, vol. 1, no. 4, p. 473.
Voisin, C., Del Fatti, N., Christofilos, D., and Vallee, F., J. Phys. Chem. B, 2001, vol. 105, p. 2264.
Volkov, A.N., Sevilla, C., and Zhigilei, L.V., Appl. Surf. Sci., 2007, vol. 253, p. 6394.
Boulais, E., Lachaine, R., and Meunier, M., Nano Letters, 2012, vol. 12, p. 4763.
Shelaev, I.V., Gostev, F.E., Vishnev, M.I., Shkuropatov, A.Y., Ptushenko, V.V., Mamedov, M.D., Sarkisov, O.M., and Nadtochenko, V.A., Semenov, A.Yu., and Shuvalov, V.A., J. Photochem. Photobiol., 2011, vol. 104, p. 44.
Zabetakis, K., Ghann, W.E., Kumar, S., and Daniel, M.C., Gold Bull., 2012, vol. 45, p. 203.
Le Ru, E. and Etchegoin, P., MatLab SPlaC v1.0. 2008. http://www.victoria.ac.nz/raman/book/codes.aspx
Gruebele, M. and Zewail, A.H., J. Chem. Phys., 1993, vol. 98, p. 883.
Sarkisov, O.M. and Umanskii, S.Ya., Usp. Khim., 2001, vol. 70, no. 6, p. 515.
Aiboushev, A., Gostev, F., Shelaev, I., Kostrov, A., Kanaev, A., Museur, L., Traore, M., Sarkisov, O., and Nadtochenko, V., Photochem. Photobiol. Sci., 2013, vol. 12, no. 4, p. 631.
Schiebener, P., Straub, J., Levelt, Sengers, J.M.H., and Gallagher, J.S., J. Phys. Chem. Ref. Data, 1990, vol. 19, no. 3, p. 677.
Boulais, E., Lachaine, R., and Meunier, M., J. Phys. Chem. C, 2013, vol. 117, p. 9386.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.V. Aibush, A.A. Astaf’ev, F.E. Gostev, N.N. Denisov, A.A. Titov, I.V. Shelaev, A.M. Shakhov, V.A. Nadtochenko, 2015, published in Khimiya Vysokikh Energii, 2015, Vol. 49, No. 5, pp. 377–381.
Rights and permissions
About this article
Cite this article
Aibush, A.V., Astaf’ev, A.A., Gostev, F.E. et al. Pulse heating of water at the surface of gold nanoparticles: Femtosecond laser spectroscopy of energy relaxation of aqueous colloid of plasmonic nanoparticles under strong excitation conditions. High Energy Chem 49, 336–340 (2015). https://doi.org/10.1134/S0018143915050021
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143915050021