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Thermodynamic Properties of Fluorapophyllite-(K) and Hydroxyapophyllite-(K)

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Abstract

A thermochemical study of natural apophyllite-group minerals, fluorapophyllite-(K) KCa4[Si8O20]F ⋅ 8H2O (Maharashtra, India) (I) and hydroxyapophyllite-(K) KCa4[Si8O20]OH ⋅ 8H2O (Norilsk, Russia) (II), was carried out on a high-temperature heat-flux Tian-Calvet Setaram (France) microcalorimeter using the melt solution calorimetry method. The first data on the enthalpies of formation from elements are obtained for the minerals studied: –13205 ± 13 kJ/mol (I) and –13054 ± 20 kJ/mol (II). The values of their standard entropies and Gibbs energies of formation are estimated.

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REFERENCES

  1. C. I. Chalokwu and Y.-C. Yau, “Hydroxyapophyllite in hornfels Beneas the Duluth Complex, Northeastern Minnesota,” Can. Mineral. 23, 489–490 (1985).

    Google Scholar 

  2. G. Y. Chao, “The refinement of the crystal structure of apophyllite. II. Determination of the hydrogen positions by X-ray diffraction,” Am. Mineral. 56, 1234–1242 (1971).

    Google Scholar 

  3. N. V. Chukanov, Infrared Spectra of Mineral Species: Extended Library (Springer–Verlag GmbH, Dordrecht–Heidelberg–New York–London, 2014).

    Book  Google Scholar 

  4. A. H. Colville, C. P. Anderson, and P. M. Black, “Refinement of the structure of apophyllite. I. X-ray diffraction and physical properties,” Am. Mineral. 56, 1222–1233 (1971).

    Google Scholar 

  5. Database of Raman Spectroscopy, X-ray Diffraction and Chemistry of Minerals. http://www.rruff.info/

  6. P. J. Dunn, R. C. Rouse, J. A. Norberg, and D. R. Peacor, “Hydroxyapophyllite, a new mineral, and a redefinition of the apophyllite group. I. Description, occurrences, and nomenclature. II. Crystal structure,” Am. Mineral. 63, 196–202 (1978).

    Google Scholar 

  7. R. L. Frost and Y. Xi, “Raman spectroscopic study of the minerals apophyllite–(KF) KCa4[Si8O20]F · 8H2O and apophyllite–(KOH) KCa4[Si8O20](F,OH) · 8H2O,” J. Mol. Struct. 1028, 200–207 (2012).

    Article  Google Scholar 

  8. R. L. Frost and Y. Xi, “Thermoanalytical study of the minerals apophyllite–(KF) KCa4[Si8O20]F · 8H2O and apophyllite–(KOH) KCa4[Si8O20](F,OH) · 8H2O,” J. Therm. Anal. Calorim. 112, 607–614 (2013).

    Article  Google Scholar 

  9. S. V. Goryainov, A. S. Krylov, Y. Pan, I. A. Madyukov, M. B. Smirnov, and A. N. Vtyurin, “Raman investigation of hydrostatic and nonhydrostatic compressions of OH– and F–apophyllites up to 8 GPa,” J. Raman Spectrosc. 4 (3), 439–447 (2012).

    Article  Google Scholar 

  10. IMA (2017) International Mineralogical Association, 2017. http://www.ima–mineralogy.org

  11. I. A. Kiseleva and L. P. Ogorodova, “Application of high-temperature dissolution calorimetry for determination of enthalpy of formation of hydroxyl-bearing minerals: evidence from talc and tremolite,” Geokhimiya, No. 12, 1745–1755 (1983).

    Google Scholar 

  12. I. A. Kiseleva, A. Navrotsky, I. A. Belitsky, and B. A. Fursenko, “Thermochemical study of calcium zeolites–heulandite and stilbite,” Am. Mineral. 86, 448–455 (2001).

    Article  Google Scholar 

  13. I. A. Kiseleva, L. P. Ogorodova, N. D. Topor, and O. G. Chigareva, “Thermochemical study of the CaO–MgO–SiO2. system,” Geokhimiya, No. 12, 1811–1825 (1979).

    Google Scholar 

  14. Yu. D. Lazebnik, N. V. Zayakina, and D. A. Kulagina, “Apophyllite as a product of supergene alteration of charoite,” Dokl. Akad. Nauk SSSR 237 (6), 934–936 (1977).

    Google Scholar 

  15. M. Mao and Y. Pan, “Radiation–induced defects in apophyllites. I. The NH2 free radical in fluorapophyllite,” Eur. J. Mineral. 21, 317–324 (2009).

    Article  Google Scholar 

  16. G. F. Marriner, J. Tarney, and J. I. Langford, “Apophyllite group: effects of chemical substitutions on dehydration behavior, recrystallization products and cell parameters,” Mineral. Mag. 54, 567–577 (1990).

    Article  Google Scholar 

  17. Minerals. A Hand Book, Ed. by F. V. Chukhrov (Nauka, Moscow, 1992), Vol. 4 [in Russian].

    Google Scholar 

  18. G. B. Naumov, B. N. Ryzhenko, and I. L. Khodakovsky, A Hand-Book of Thermodynamic Values (for Geologists) (Atomizdat, Moscow, 1971) [in Russian].

    Google Scholar 

  19. L. P. Ogorodova, I. A. Kiseleva, L. V. Mel’chakova, M. F. Vigasina, and E. M. Spiridonov, “Calorimetric determination of the enthalpy of formation for pyrophyllite,” Russ. G. Phys. Chem. A 85 (9), 1492–1494 (2011).

    Article  Google Scholar 

  20. L. P. Ogorodova, L. V. Melchakova, I. A. Kiseleva, and I. A. Belitsky, “Thermochemical study of natural pollucite,” Thermochim. Acta 403, 251–256 (2003).

    Article  Google Scholar 

  21. E. Prince, “Refinement of the crystal structure of apophyllite. III. Determination of the hydrogen positions by neutron diffraction,” Am. Mineral. 56, 1243–1251 (1971).

    Google Scholar 

  22. R. A. Robie and B. S. Hemingway, “Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar (105 Pascals) pressure and at higher temperatures,” U.S. Geol. Surv. Bull., No. 2131, (1995)

  23. Ya. I. Ryskin and G. P. Stavitskaya, “Asymmetry of the water molecule in crystal hydrates: IR spectra of dioptese and apophyllite,” Russ. Chem Bull. 39 (8), 1610–1614 (1990).

    Article  Google Scholar 

  24. K. M. Specht, M. Jackson, B. Sunkel, and M. A. Boucher, “Synthesis of a functianalized sheet silicate derived from apophyllite and further modification by hydrosilylation,” Appl. Clay Sci. 47, 212–215 (2010).

    Article  Google Scholar 

  25. E. M. Spiridonov and Yu. D. Gritsenko, Low-Grade Metamorphism and Co–Ni–Sb–As Mineralization in the Norilsk Ore Field (Nauchnyi Mir, Moscow, 2009) [in Russian].

    Google Scholar 

  26. E. M. Spiridonov, “Apophyllite from one of deposits of the North Kazakhstan,” Vestn. Mosk. Univ., No. 4, 66–68 (1964).

  27. E. M. Spiridonov, V. M. Ladygin, V. K. Stepanov, et al., Metavolcanoc Rocks of the Prehnite–Pumpelleyite Facies of the Trap Formation of the Norilsk District, Siberian Platform (MGU, Moscow, 2000) [in Russian].

    Google Scholar 

  28. K. Ståhl, Ǻ. Kvick, and S. Ghose, “A neutron diffraction and thermogravimetric study of the hydrogen bonding and dehydration behavior in fluorapophyllite, KCa4(Si8O20)F·8H2O, and its partially dehydrated form,” Acta Cryst. B43, 517–523 (1987).

    Article  Google Scholar 

  29. The International Centre for Diffraction Data, 2013. http://www.icdd.com.

  30. Thermodynamic Properties of Individual Substances. A Reference Book, Ed. by V. P. Glushko (Nauka, Moscow, 1972), Vol. 4, Book 2 [in Russian]

  31. R. R. Westrich and A. Navrotsky, “Some thermodynamic properties of fluor-apatite, fluorpargasite, and fluorphlogopite,” Am. J. Sci. 281 (8), 1091–1099 (1981).

    Article  Google Scholar 

  32. R. Włodyka and R. Wrzalic, “Apophyllite from the Międzyrzecze sill near Bielsco–Biała, the type area of the teschenite–picrite association,” Mineral. Polonica 35 (1), 19–32 (2004).

    Google Scholar 

  33. B. Young, A. Dyer, N. Hubbard, and R. E. Starkey, “Apophyllite and other zeolite–type minerals from the Whin Sill of the northern Pennines,” Mineral. Mag. 55, 203–207 (1991).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

We are grateful to prof. E.M. Spiridonov (Moscow State University, Geological Faculty) for given fluorapophyllite-(K) sample, attention to and support of this work, as well as the useful recommendations, which significantly improved this manuscript.

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Authors and Affiliations

  1. Faculty of Geology, Moscow State University, 119234, Moscow, Russia

    L. P. Ogorodova, L. V. Melchakova, M. F. Vigasina, Yu. D. Gritsenko, D. A. Ksenofontov & I. A. Bryzgalov

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  1. L. P. Ogorodova
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  2. L. V. Melchakova
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  3. M. F. Vigasina
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  4. Yu. D. Gritsenko
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  5. D. A. Ksenofontov
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  6. I. A. Bryzgalov
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Correspondence to L. P. Ogorodova.

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Translated by M. Bogina

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Ogorodova, L.P., Melchakova, L.V., Vigasina, M.F. et al. Thermodynamic Properties of Fluorapophyllite-(K) and Hydroxyapophyllite-(K). Geochem. Int. 57, 805–811 (2019). https://doi.org/10.1134/S0016702919070097

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  • DOI: https://doi.org/10.1134/S0016702919070097

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