Skip to main content
SpringerLink
Log in

Unusual platinum complexes in the gas phase

  • Physical Chemistry
  • Published:
Doklady Physical Chemistry Aims and scope Submit manuscript

Abstract

Previously unknown cationic platinum complexes Pt(C5H4N)(C5H5N)+ and Pt(C5H4N)+, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Schmidt, M.W., Baldridge, K.K., Boatz, I.A., et al., J. Comput. Chem., 1993, vol. 14, pp. 1347–1363.

    Article  CAS  Google Scholar 

  2. Zhao, Y. and Truhlar, D., Theor. Chim. Acta, 2008, vol. 120, pp. 215–241.

    Article  CAS  Google Scholar 

  3. Adamo, C. and Barone, V., J. Chem. Phys., 1999, vol. 110, pp. 6158–6170.

    Article  CAS  Google Scholar 

  4. Paschoal, D., Marial, B.L., Jopes, J.F., et al., J. Comput. Chem., 2012, vol. 33, pp. 2292–2302.

    Article  CAS  Google Scholar 

  5. Weigend, F. and Ahlrichs, R., Phys. Chem. Chem. Phys., 2005, vol. 7, no. 18, pp. 3297–3305.

    Article  CAS  Google Scholar 

  6. Feller, D., J. Comput. Chem., 1996, vol. 17, pp. 1571–1586.

    Article  CAS  Google Scholar 

  7. Schuchardt, K.L., Didier, B.T., Todd, E., et al., J. Chem. Inf. Modeling, 2007, vol. 47, pp. 1045–1052.

    Article  CAS  Google Scholar 

  8. Omae, I., Chem. Rev., 1979, vol. 79, pp. 287–321.

    Article  CAS  Google Scholar 

  9. Cotton, A.F. and Poli, R., Organometallics, 1987, vol. 6, pp. 1751–1756.

    Article  Google Scholar 

  10. Lapointe, D. and Fagnou, K., Chem. Lett., 2010, vol. 39, pp. 1118–1126.

    Article  Google Scholar 

  11. Johnson, K.R.D. and Hayes, P.G., Chem. Soc. Rev., 2013, vol. 42, pp. 1947–1960.

    Article  CAS  Google Scholar 

  12. Crespo, M., Inorganics, 2014, vol. 2, pp. 115–131.

    Article  CAS  Google Scholar 

  13. Thompson, M.E., Baxter, S.M., Bulls, A.R., Burger, D.J., Nolan, M.C., Santasiero, B.D., Schaefer, W.P., and Bercaw, J.E., J. Am. Chem. Soc., 1987, vol. 109, pp. 203–219.

    Article  CAS  Google Scholar 

  14. Krut’ko, D.P., Kirsanov, R.S., Belov, S.A., Borzov, M.V., Churakov, A.V., and Howard, J.A.K., Polyhedron, 2007, vol. 26, pp. 2864–2870.

    Article  Google Scholar 

  15. Esteruelas, M.A., Forcen, E., Olivan, M., and Onate, E., Organometallics, 2008, vol. 27, pp. 6188–6192.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. A. Markov, I. A. Yakushev, A. V. Churakov, I. P. Stolyarov, N. V. Cherkashina, M. N. Vargaftik, A. E. Gekhman & I. I. Moiseev

  2. Institute of Problems in Chemical Physics, Russian Academy of Sciences, pr. Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    A. B. Kornev

Authors
  1. A. A. Markov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Yakushev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Churakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. P. Stolyarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Cherkashina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. B. Kornev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. N. Vargaftik
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. E. Gekhman
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. I. I. Moiseev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Markov.

Additional information

Original Russian Text © A.A. Markov, I.A. Yakushev, A.V. Churakov, I.P. Stolyarov, N.V. Cherkashina, A.B. Kornev, M.N. Vargaftik, A.E. Gekhman, I.I. Moiseev, 2016, published in Doklady Akademii Nauk, 2016, Vol. 468, No. 2, pp. 175–178.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Markov, A.A., Yakushev, I.A., Churakov, A.V. et al. Unusual platinum complexes in the gas phase. Dokl Phys Chem 468, 72–75 (2016). https://doi.org/10.1134/S0012501616050031

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0012501616050031

Search

Navigation