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Synthesis and Crystal Structure of Iron(II) and Cobalt(III) Complexes with Hetarylhydrazone Derived from o-Diphenylphosphinobenzaldehyde and 1-Hydrazinophthalazine

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Abstract

Reaction of 1-phthalazinylhydrazone of o-diphenylphosphinobenzaldehyde (HL) with Fe(II) and Co(II) perchlorates has led to complexes of different composition and structure: [Fe(HL)2](ClO4)2 · H2O (1) and [CoL2](ClO4) · H2O (2) in spite of the use of salts with the same anion. Со2+ ion undergoes oxidation to Co3+ upon complexation. The structure of the complexes has been established by NMR spectroscopy in solution and by X-ray diffraction in crystal. X-ray diffraction has shown that complexing metal ions have octahedral structure. Compound 2 forms two independent molecules in crystal.

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ACKNOWLEDGMENTS

Elemental analysis was performed in the Laboratory of Microanalysis, Southern Federal University.

Funding

The structural studies in this work were performed under financial support of the State Assignment no. АААА-А19-119092390076-7 for the Institute of Problems in Chemical Physics, Russian Academy of Sciences (V.V. Tkachev, A.N. Utenyshev, and S.M. Aldoshin).

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Authors and Affiliations

  1. Southern Federal University, 344006, Rostov-on-Don, Russia

    L. D. Popov, S. A. Borodkin & I. N. Shcherbakov

  2. Institute of Problems in Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. V. Tkachev, A. N. Utenyshev &  S. M. Aldoshin

Authors
  1. L. D. Popov
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  2. S. A. Borodkin
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  3. V. V. Tkachev
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  4. A. N. Utenyshev
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  5. I. N. Shcherbakov
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  6. S. M. Aldoshin
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Corresponding author

Correspondence to L. D. Popov.

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Translated by I. Kudryavtsev

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Popov, L.D., Borodkin, S.A., Tkachev, V.V. et al. Synthesis and Crystal Structure of Iron(II) and Cobalt(III) Complexes with Hetarylhydrazone Derived from o-Diphenylphosphinobenzaldehyde and 1-Hydrazinophthalazine. Dokl Chem 501, 249–254 (2021). https://doi.org/10.1134/S001250082112003X

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  • DOI: https://doi.org/10.1134/S001250082112003X

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