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Reduction of Acridine and 9-Chloroacridine with Red Phosphorus in the KOH/DMSO System

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Abstract

Acridine reacts with red phosphorus in the KOH/DMSO(H2O) system on heating (100°C, 3 h) to give 9,10-dihydroacridine regioselectively in quantitative yield. Under similar conditions, 9-chloroacridine reacts with Pred/KOH/DMSO(H2O) system to afford 9,10-dihydroacridine and acridone in 51 and 40% yield, respectively.

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ACKNOWLEDGMENTS

This work was performed using equipment of the Shared Facility Center, Baikal Analytical Center, Siberian Branch, Russian Academy of Sciences.

Funding

This work was supported by the Russian Foundation for Basic Research (project no. 17–03–00739).

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Authors and Affiliations

  1. Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    V. A. Kuimov, N. K. Gusarova, S. F. Malysheva, T. V. Kon’kova &  B. A. Trofimov

Authors
  1. V. A. Kuimov
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  2. N. K. Gusarova
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  3. S. F. Malysheva
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  4. T. V. Kon’kova
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  5. B. A. Trofimov
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Corresponding author

Correspondence to B. A. Trofimov.

Additional information

Translated by I. Kudryavtsev

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Kuimov, V.A., Gusarova, N.K., Malysheva, S.F. et al. Reduction of Acridine and 9-Chloroacridine with Red Phosphorus in the KOH/DMSO System. Dokl Chem 487, 177–179 (2019). https://doi.org/10.1134/S001250081907005X

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  • DOI: https://doi.org/10.1134/S001250081907005X

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