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Crystal Structure of Two-Dimensional Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Derived from 4,4'-Dipyridyl Sulfide

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Abstract

A new complex of general formula {[Cu(dps)2(DMSO)2](ClO4)2}n has been obtained with the aim to study the effect of perchlorate anion on the structure of coordination polymer based on 4,4'-dipyridyl sulfide. It has been established by X-ray diffraction that the compound has a layered 2D polymer structure. Each copper(II) ion is in a pseudo-octahedral donor environment. Perchlorate anions are disposed in the network voids of the polymer complex.

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ACKNOWLEDGMENTS

This work was supported by the Southern Federal University (internal grant no. VnGr–07/2017–29) and the Federal Agency of Scientific Organizations (State registration no. 0089–2014–0009).

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Authors and Affiliations

  1. Southern Federal University, 344090, Rostov-on-Don, Russia

    Yu. P. Tupolova, I. N. Shcherbakov, L. D. Popov & V. A. Chetverikova

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. V. Tkachev, G. V. Shilov &  S. M. Aldoshin

Authors
  1. Yu. P. Tupolova
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  2. I. N. Shcherbakov
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  3. L. D. Popov
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  4. V. V. Tkachev
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  5. V. A. Chetverikova
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  6. G. V. Shilov
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  7. S. M. Aldoshin
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Correspondence to Yu. P. Tupolova.

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Translated by I. Kudryavtsev

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Tupolova, Y.P., Shcherbakov, I.N., Popov, L.D. et al. Crystal Structure of Two-Dimensional Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Derived from 4,4'-Dipyridyl Sulfide. Dokl Chem 483, 304–307 (2018). https://doi.org/10.1134/S001250081812008X

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  • DOI: https://doi.org/10.1134/S001250081812008X

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