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Bis[1,3]thiazolo[4,5-f:5',4'-h]thieno[3,4-b]quinoxaline Derivatives as New Building Blocks of Polymers for Organic Electronics

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Abstract

New derivatives of bis[1,3]thiazolo[4,5-f:5',4'-h]thieno[3,4-b]quinoxaline containing the fused thiadiazoloquinoxaline moiety have been prepared. Monomer M1 shows strong light absorption within 600–800 nm due to intramolecular charge transfer. The optical bandgap E optg determined from the absorption edge in a film is 1.44 eV. The HOMO and LUMO levels are–5.44 and–3.12 eV, respectively. The new structural fragment has a rather low frontier molecular orbital energies and a small bandgap; therefore, it is a promising building block for the synthesis of polymers for organic electronics.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    S. A. Kuklin, I. O. Konstantinov, A. S. Peregudov, A. R. Khokhlov & M. L. Keshtov

  2. Moscow State University, Moscow, 119991, Russia

    I. E. Ostapov & E. E. Makhaeva

Authors
  1. S. A. Kuklin
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  2. I. O. Konstantinov
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  3. A. S. Peregudov
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  4. I. E. Ostapov
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  5. E. E. Makhaeva
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  6. A. R. Khokhlov
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  7. M. L. Keshtov
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Correspondence to S. A. Kuklin.

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Original Russian Text © S.A. Kuklin, I.O. Konstantinov, A.S. Peregudov, I.E. Ostapov, E.E. Makhaeva, A.R. Khokhlov, M.L. Keshtov, 2018, published in Doklady Akademii Nauk, 2018, Vol. 482, No. 3.

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Kuklin, S.A., Konstantinov, I.O., Peregudov, A.S. et al. Bis[1,3]thiazolo[4,5-f:5',4'-h]thieno[3,4-b]quinoxaline Derivatives as New Building Blocks of Polymers for Organic Electronics. Dokl Chem 482, 207–211 (2018). https://doi.org/10.1134/S0012500818090070

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  • DOI: https://doi.org/10.1134/S0012500818090070

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